Protein scaffold of a designed metalloenzyme enhances the chemoselectivity in sulfoxidation of thioanisole.

Protein scaffold of a designed metalloenzyme enhances the chemoselectivity in sulfoxidation of thioanisole.

Chemical communications (Cambridge, England) (2008-03-28)

Jun-Long Zhang, Dewain K Garner, Lei Liang, Qian Chen, Yi Lu

ZUSAMMENFASSUNG

We demonstrate that incorporation of MnSalen into a protein scaffold enhances the chemoselectivity in sulfoxidation of thioanisole and find that both the polarity and hydrogen bonding of the protein scaffold play an important role in tuning the chemoselectivity.

MATERIALIEN

Produktnummer

Marke

Produktbeschreibung

T28002

Sigma-Aldrich

Thioanisol, ReagentPlus^®, ≥99%

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