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Personal exposure to volatile organic compounds in the Czech Republic.

Journal of exposure science & environmental epidemiology (2012-06-07)
Vlasta Svecova, Jan Topinka, Ivo Solansky, Radim J Sram
ZUSAMMENFASSUNG

Personal exposures to volatile organic compounds (VOCs) were measured in the three industrial cities in the Czech Republic, Ostrava, Karvina and Havirov, while the city of Prague served as a control in a large-scale molecular epidemiological study identifying the impacts of air pollution on human health. Office workers from Ostrava and city policemen from Karvina, Havirov and Prague were monitored in the winter and summer of 2009. Only adult non-smokers participated in the study (N=160). Radiello-diffusive passive samplers were used to measure the exposure to benzene, toluene, ethylbenzene, meta- plus para-xylene and ortho-xylene (BTEX). All participants completed a personal questionnaire and a time-location-activity diary (TLAD). The average personal BTEX exposure levels in both seasons were 7.2/34.3/4.4/16.1 μg/m(3), respectively. The benzene levels were highest in winter in Karvina, Ostrava and Prague: 8.5, 7.2 and 5.3 μg/m(3), respectively. The personal exposures to BTEX were higher than the corresponding stationary monitoring levels detected in the individual localities (P<0.001; except m,p-xylene in summer). The indoor environment, ETS (environmental tobacco smoke), cooking, a home-heating fireplace or gas stove, automobile use and being in a restaurant were important predictors for benzene personal exposure. Ostrava's outdoor benzene pollution was a significant factor increasing the exposure of the Ostrava study participants in winter (P<0.05).

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

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Xylole, histological grade
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Xylole, reagent grade
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o-Xylen, reagent grade, ≥98.0%
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p-Xylen, suitable for HPLC, ≥99%
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p-Xylen, ReagentPlus®, 99%
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radiello Kartuschen-Adsorbenzien, for sampling BTEX and VOCs (CS2 Desorption), matrix SS net (100 mesh, 5.8 mm diam.), activated with activated charcoal (30-50 mesh), pk of 20
radiello Kartuschen-Adsorbenzien, for sampling Aldehydes, matrix SS net with 2,4-DNPH coated FLORISIL®, pk of 20
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radiello Diffusionskörper, white, configured for general use, pk of 20
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radiello Dreieckige Trägerplatte, pk of 20
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radiello Kartuschen-Adsorbenzien, for sampling Ammonia (NH3), matrix microporous PE impregnated with phosphoric acid, pk of 20
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o-Xylen, analytical standard
radiello Diffusionskörper, yellow, configured for reduced sampling rates, pk of 20
radiello Diffusionskörper, blue, configured for sampling light sensitive compounds, pk of 20
radiello Kartuschen-Adsorbenzien, for sampling BTEX and VOCs (thermal desorption), matrix SS net (3 x 8 μm, 4.8 mm diam.), Carbograph, pk of 20
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m-Xylol, analytical standard
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radiello Methylenblau-Kalibrierstandard für H2S (Schwefelwasserstoff), pkg of 100 mL
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Ethylbenzol -Lösung, suitable for NMR (reference standard), 10% in chloroform-d (99.8 atom % D), NMR tube size 5 mm × 8 in. , ultra-thin wall