If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
About This Item
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Product Name
Benzaldehyde, purified by redistillation, ≥99.5%
InChI key
HUMNYLRZRPPJDN-UHFFFAOYSA-N
InChI
1S/C7H6O/c8-6-7-4-2-1-3-5-7/h1-6H
SMILES string
O=Cc1ccccc1
vapor density
3.7 (vs air)
vapor pressure
4 mmHg ( 45 °C)
assay
≥99.5%
form
liquid
autoignition temp.
374 °F
purified by
redistillation
expl. lim.
1.4 %, 20 °F
refractive index
n20/D 1.545 (lit.)
pH
5.9 (20 °C)
bp
178-179 °C (lit.)
mp
−26 °C (lit.)
density
1.044 g/cm3 at 20 °C (lit.)
functional group
aldehyde
phenyl
Quality Level
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This Item | B1334 | 12010 | W212717 |
|---|---|---|---|
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 400 |
| assay ≥99.5% | assay ≥99% | assay ≥99.0% (GC) | assay ≥98% |
| form liquid | form liquid | form liquid | form liquid |
| refractive index n20/D 1.545 (lit.) | refractive index n20/D 1.545 (lit.) | refractive index n20/D 1.545 (lit.) | refractive index n20/D 1.545 (lit.) |
| bp 178-179 °C (lit.) | bp 178-179 °C (lit.) | bp 178-179 °C (lit.) | bp 178-179 °C (lit.) |
| mp −26 °C (lit.) | mp −26 °C (lit.) | mp −26 °C (lit.) | mp −26 °C (lit.) |
Application
- Cinnamaldehyde, cinnamic acid, ethyl cinnamate, benzoic acid, benzyl alcohol, benzyl benzoate and hydrobenzamide etc.[1]
- Triphenylmethane derivatives by condensation with phenols, aromatic amines, and benzene. This reaction is useful for the production of malachite green dyes.[1]
- Benzoylborane by reacting with borylmagnesium bromides.[2]
- Multi-benzaldehyde functionalized poly(ethylene glycol) analog which is used as a cross-linker to develop an injectable hydrogel system.[3]
General description
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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