197637

Imidazole sodium derivative

Name: Imidazole sodium derivative
Brand: ALDRICH
Price: 135 EUR

technical grade

Synonym(s):

Imidazolylsodium, Sodium imidazolide

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About This Item

Empirical Formula (Hill Notation):

C₃H₃N₂Na

CAS Number:

5587-42-8

Molecular Weight:

90.06

NACRES:

NA.22

PubChem Substance ID:

24851839

eCl@ss:

39161001

UNSPSC Code:

12352005

EC Number:

226-988-5

MDL number:

MFCD00064314

Beilstein/REAXYS Number:

3569312

Key Documents

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Product Name

Imidazole sodium derivative, technical grade

InChI key

ITAWMPSVROAMOE-UHFFFAOYSA-N

InChI

1S/C3H3N2.Na/c1-2-5-3-4-1;/h1-3H;/q-1;+1

SMILES string

[Na]n1ccnc1

grade

technical grade

mp

284 °C (dec.) (lit.)

Quality Level

100

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1 of 4

This Item	56760	307815	206288
Sigma-Aldrich 197637 Imidazole sodium derivative	Sigma-Aldrich 56760 Triethoxy-3-(2-imidazolin-1-yl)propylsilane	Sigma-Aldrich 307815 Sodium metasilicate	Sigma-Aldrich 206288 Sodium hexachlororhodate(III)
Quality Level 100	Quality Level 100	Quality Level 200	Quality Level 100
mp 284 °C (dec.) (lit.)	mp -	mp -	mp -
grade technical grade	grade -	grade -	grade -

Application

Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin[1].

pictograms

GHS05,GHS07

signalword

Danger

hcodes

H302 + H312 + H332,H314

pcodes

P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Photoaffinity labelling of mitochondrial NADH dehydrogenase with arylazidoamorphigenin, an analogue of rotenone.

F G Earley et al.

The Biochemical journal, 224(2), 525-534 (1984-12-01)

A photoaffinity-labelling analogue of the respiratory inhibitor rotenone was synthesized from the naturally occurring rotenoid amorphigenin. The analogue inhibits NADH-ubiquinone oxidoreductase activity at concentrations comparable with those of rotenone. Photolysis of the radiolabelled analogue bound to isolated NADH-ubiquinone oxidoreductase resulted

Structure and nature of manganese(II) imidazole complexes in frozen aqueous solutions.

Sun Un

Inorganic chemistry, 52(7), 3803-3813 (2013-03-21)

A common feature of a large majority of the manganese metalloenzymes, as well as many synthetic biomimetic complexes, is the bonding between the manganese ion and imidazoles. This interaction was studied by examining the nature and structure of manganese(II) imidazole

Adapting fluorescence resonance energy transfer with quantum dot donors for solid-phase hybridization assays in microtiter plate format.

Eleonora Petryayeva et al.

Langmuir : the ACS journal of surfaces and colloids, 29(3), 977-987 (2013-01-10)

Methods have been developed for the solid-phase detection of nucleic acids using mixed films of quantum dots (QDs) and oligonucleotide probes in microtiter plates. Polystyrene microwells were functionalized with multidentate imidazole ligands to immobilize QDs. Oligonucleotide hybridization was transduced using

Effects of imidazole deprotonation on vibrational spectra of high-spin iron(II) porphyrinates.

Chuanjiang Hu et al.

Inorganic chemistry, 52(6), 3170-3177 (2013-03-09)

The effects of the deprotonation of coordinated imidazole on the vibrational dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes

A family of single-isomer, dicationic cyclodextrin chiral selectors for capillary electrophoresis: mono-6(A)-ammonium-6(C)-butylimidazolium-β-cyclodextrin chlorides.

Yun Dai et al.

Electrophoresis, 34(6), 833-840 (2013-01-22)

The first member of the single-isomer, dicationic cyclodextrin (CD) family, 6(A)-ammonium-6(C)-butylimidazolium-β-cyclodextrin chlorides (AMBIMCD), has been synthesized, analytically characterized, and used to separate a variety of acidic enantiomers and amino acids by CE. Starting from mono-6(A)-azido-β-cyclodextrin, the cationic imidazolium and ammonium

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Imidazole sodium derivative