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Merck

177865

Dichloromethane-d2

99.5 atom % D

Synonym(s):

Dideuteromethylenechloride, Methylene chloride-d2

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10 G

CZK 9,100.00

10 X 1 ML

CZK 9,650.00

25 G

CZK 17,300.00

CZK 9,100.00


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About This Item

Linear Formula:
CD2Cl2
CAS Number:
Molecular Weight:
86.94
Beilstein:
1733318
EC Number:
MDL number:
UNSPSC Code:
12142201
PubChem Substance ID:
NACRES:
NA.21

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vapor pressure

25.59 psi ( 55 °C)
7.63 psi ( 20 °C)

Quality Level

isotopic purity

99.5 atom % D

Assay

≥99.00% (GC)

form

liquid

packaging

ampule of 1mL, 10g
glass bottle of 25g

technique(s)

NMR: suitable

impurities

≤0.0100% water
water

refractive index

n20/D 1.422 (lit.)

bp

40 °C (lit.)

mp

-97 °C (lit.)

density

1.362 g/mL at 25 °C (lit.)

mass shift

M+2

SMILES string

[2H]C([2H])(Cl)Cl

InChI

1S/CH2Cl2/c2-1-3/h1H2/i1D2

InChI key

YMWUJEATGCHHMB-DICFDUPASA-N

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1 of 4

This Item
2333661.13720296163
technique(s)

NMR: suitable

technique(s)

NMR: suitable

technique(s)

-

technique(s)

NMR: suitable

assay

≥99.00% (GC)

assay

99% (CP)

assay

-

assay

≥99.00% (GC)

isotopic purity

99.5 atom % D

isotopic purity

99.96 atom % D

isotopic purity

-

isotopic purity

≥99.5 atom % D

mass shift

M+2

mass shift

M+2

mass shift

-

mass shift

M+2

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

General description

Dichloromethane-d2 is a deuterated derivative of dichloromethane. It participates as a solvent during the NMR spectral analysis of polymers.[1]

Application

Dichloromethane-d2 has been employed as a deuterated solvent for sample preparation in NMR analysis.[2]

Other Notes

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number

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Absolute Raman intensities, force constants, and electro-optical parameters of CH2Cl2, CD2Cl2 and CHDCl2.
Escribano R, et al.
Molecular Physics, 37(2), 361-377 (1979)
Determination of the three-dimensional, solution-phase structure of the macrolide antibiotic oxolide in CD2Cl2 and D2O from NMR constraints.
Steinmetz WE, et al.
Magnetic Resonance in Chemistry, 43(1), 16-20 (2005)
Applications and new developments of the direct exponential curve resolution algorithm (DECRA). Examples of spectra and magnetic resonance images.
Windig W, et al.
Journal of Chemometrics, 13(2), 95-110 (1999)
Michael Weber et al.
Analytical and bioanalytical chemistry, 407(11), 3115-3123 (2014-11-25)
Quantitative nuclear magnetic resonance (qNMR) spectroscopy is employed by an increasing number of analytical and industrial laboratories for the assignment of content and quantitative determination of impurities. Within the last few years, it was demonstrated that (1)H qNMR can be
Ting Li et al.
Environmental science and pollution research international, 22(15), 11792-11800 (2015-04-11)
We surveyed the occurrence of nine N-nitrosamine species in ten bottled drinking waters from supermarket and other water samples including raw waters, finished waters, and distribution system waters from nine municipal drinking water treatment plants in eight cities of Jiangsu

Related Content

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

NMR spektroskopie objasňuje strukturu a čistotu molekul prostřednictvím jaderných spinových stavů v silném magnetickém poli.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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