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Merck

215813

Potassium hydride

greener alternative

30 wt % dispersion in mineral oil

Synonym(s):

Potassium monohydride

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75 G

CZK 6,920.00

300 G

CZK 23,100.00

CZK 6,920.00


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About This Item

Linear Formula:
KH
CAS Number:
Molecular Weight:
40.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-704-8
MDL number:

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Product Name

Potassium hydride, 30 wt % dispersion in mineral oil

InChI key

NTTOTNSKUYCDAV-UHFFFAOYSA-N

InChI

1S/K.H

SMILES string

[K]

form

slurry

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

30 wt % dispersion in mineral oil

greener alternative category

Quality Level

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This Item
452912223441686034
Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

form

slurry

form

powder (moist, paste-like)

form

powder

form

pellets

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

concentration

30 wt % dispersion in mineral oil

concentration

60 % dispersion in mineral oil

concentration

-

concentration

-

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Potassium hydride can be used for following applications:
  • Deprotonation: As a strong base, potassium hydride effectively deprotonates hydroxyl groups of monomers, generating alkoxide ions. These ions facilitate the ring-opening polymerization of monosubstituted oxiranes.
  • Strong Base in Williamson Ether Synthesis: It is employed to generate alkoxides from alcohols, which subsequently react with alkyl halides to form ethers.
  • Reducing Agent: Potassium hydride can reduce hindered boranes and borates to trialkyl borohydrides. It also facilitates the reduction of ketones and alkyl halides.
  • Alkylation and Enolate Formation: It aids in the formation of enolates from ketones, which can be utilized in one-pot alkylation-cyclization reactions.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Water-react 1

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

No data available

flash_point_c

No data available

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Patnaik P et al.
A Comprehensive Guide to the Hazardous Properties of Chemical Substances null
Potassium hydride in paraffin: A useful base for organic synthesis.
Taber DF and Nelson CG
The Journal of Organic Chemistry, 71(23), 8973-8974 (2006)
Mayumi Tada et al.
The European journal of neuroscience, 39(11), 1720-1728 (2014-01-11)
Calcium imaging of individual neurons is widely used for monitoring their activity in vitro and in vivo. Synthetic fluorescent calcium indicator dyes are commonly used, but the resulting calcium signals sometimes suffer from a low signal-to-noise ratio (SNR). Therefore, it
David K Packham et al.
The New England journal of medicine, 372(3), 222-231 (2014-11-22)
Hyperkalemia (serum potassium level, >5.0 mmol per liter) is associated with increased mortality among patients with heart failure, chronic kidney disease, or diabetes. We investigated whether sodium zirconium cyclosilicate (ZS-9), a novel selective cation exchanger, could lower serum potassium levels
Pieter Clauw et al.
Plant physiology, 167(3), 800-816 (2015-01-22)
Although the response of plants exposed to severe drought stress has been studied extensively, little is known about how plants adapt their growth under mild drought stress conditions. Here, we analyzed the leaf and rosette growth response of six Arabidopsis

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How is the item Potassium hydride (215813-75G) packaged?

    1 answer
    1. The item, Potassium hydride (215813-75G), is packaged in a 3" Carbon Steel (CS) Can OVERPACK CAN (307) and is placed inside a 4 MIL POLYAMIDE BAG (114 X 216 MM). It is further contained in a 125 ML Wide Mouth White High-Density Polyethylene (HDPE) bottle with a red polypropylene (PP) cap.

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