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Merck

680966

2-Propylzinc bromide solution

0.5 M in THF

Synonym(s):

Isopropylzinc bromide

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50 ML

CZK 8,190.00

CZK 8,190.00


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About This Item

Linear Formula:
(CH3)2CHZnBr
CAS Number:
Molecular Weight:
188.38
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

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concentration

0.5 M in THF

density

0.963 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)[Zn]Br

InChI

1S/C3H7.BrH.Zn/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1

InChI key

IKQCKJSWVAERRG-UHFFFAOYSA-M

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This Item
498521290998360074
Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

density

0.963 g/mL at 25 °C

density

0.972 g/mL at 25 °C

density

0.947 g/mL at 25 °C

density

3.72 g/mL at 25 °C (lit.)

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

-

concentration

0.5 M in THF

concentration

0.5 M in THF

concentration

2.0 M in diethyl ether

concentration

-

Application

2-Propylzinc bromide solution (0.5 M in THF) has been used as a reagent in a protocol for the nickel-catalyzed dehalogenation of organic halides.[1]

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Nickel-catalyzed hydrodehalogenation of aryl halides
Weidauer Maik, et al.
Journal of Organometallic Chemistry, 729, 53-59 (2013)

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