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Merck

223433

Sodium oxalate

ACS reagent, ≥99.5%

Synonym(s):

Ethanedioic acid sodium salt, Oxalic acid disodium salt

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100 G

€42.90

500 G

€166.00

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About This Item

Linear Formula:
NaOOCCOONa
CAS Number:
Molecular Weight:
134.00
Beilstein:
3631622
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NB.24
Assay:
≥99.5%
Grade:
ACS reagent
Form:
powder

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grade

ACS reagent

description

neutrality passes test

Assay

≥99.5%

form

powder

impurities

hot H2SO4, passes test (darkened)
≤0.005% insolubles

loss

≤0.01% loss on drying

anion traces

chloride (Cl-): ≤0.002%
sulfate (SO42-): ≤0.002%

cation traces

Fe: ≤0.001%
K: ≤0.005%
NH4+: ≤0.002%
heavy metals (as Pb): ≤0.002%

SMILES string

[Na+].[Na+].[O-]C(=O)C([O-])=O

InChI

1S/C2H2O4.2Na/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2

InChI key

ZNCPFRVNHGOPAG-UHFFFAOYSA-L

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1 of 4

This Item
718043797351.02407
form

powder

form

-

form

powder

form

solid

assay

≥99.5%

assay

>99.5%

assay

≥99.99% trace metals basis

assay

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

300

grade

ACS reagent

grade

reference material

grade

-

grade

-

impurities

hot H2SO4, passes test (darkened), ≤0.005% insolubles

impurities

-

impurities

≤100.0 ppm Trace Metal Analysis

impurities

-

cation traces

Fe: ≤0.001%, NH4+: ≤0.002%, K: ≤0.005%

cation traces

-

cation traces

-

cation traces

-

General description

Sodium oxalate is a water soluble inorganic salt mainly used for the standardization of permanganate solution during titration.[1]

Application

Sodium oxalate may be used as a dispersant and a coordination agent for the electrooxidation of formic acid using a palladium nanoparticle catalyst dispersed on the purified multi-walled carbon nanotubes (P-MWCNTs).[2] In combination with sodium hydroxide, it may be used to mediate the preparation of Cu/ZrO2 catalyst from copper nitrite and zirconium nitrate solution mixture via coprecipitation method.[3]

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Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Sodium Hydroxide-Sodium Oxalate-Assisted Co-Precipitation of Highly Active and Stable Cu/ZrO2 Catalyst in the Partial Oxidation of Methanol to Hydrogen.
Chen H, et al.
Catalysis Letters, 131(3-4), 632-642 (2009)
Electrooxidation of formic acid catalyzed by Pd nanoparticles supported on multi-walled carbon nanotubes with sodium oxalate.
Bai Z, et al.
Ionics, 19(3), 543-548 (2013)
Hong-Joo Lee et al.
Bioresource technology, 130, 211-217 (2013-01-12)
The present study investigated the feasibility of the recovery and reuse oxalic acid in a multistage process for the pretreatment of a lignocellulosic biomass. Electrodialysis (ED), an electrochemical process using ion exchange membranes, was used to recover and reuse oxalic
Taiying Zhang et al.
Carbohydrate polymers, 92(1), 334-344 (2012-12-12)
Dilute oxalic acid pretreatment was applied to maple wood to improve compatibility with downstream operations, and its performance in pretreatment and subsequent enzymatic hydrolysis was compared to results for hydrothermal and dilute hydrochloric and sulfuric acid pretreatments. The highest total
Lois Fernandez et al.
Clinical biochemistry, 46(4-5), 285-288 (2012-12-12)
There are no direct comparisons of blood glucose values in samples collected with barrier serum tubes (SST) and NaF/potassium oxalate (NaF/KOx) plasma tubes. Collection of samples in SST tubes can offer considerable savings and specimen processing advantages for national level

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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