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Merck

481130

Gold(I) chloride

99.9% trace metals basis

Sinónimos:

Aurous chloride, Gold monochloride

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Fórmula lineal:
AuCl
Número CAS:
Peso molecular:
232.42
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.23

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Ensayo

99.9% trace metals basis

Formulario

powder

idoneidad de la reacción

core: gold
reagent type: catalyst

impurezas

≤1500 ppm Trace Metal Analysis

mp

289 °C (dec.) (lit.)

densidad

7.57 g/mL at 25 °C (lit.)

cadena SMILES

[Cl-].[Au+]

InChI

1S/Au.ClH/h;1H/q+1;/p-1

Clave InChI

FDWREHZXQUYJFJ-UHFFFAOYSA-M

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Este artículo
379948334049484385
form

powder

form

solid

form

powder

form

liquid

assay

99.9% trace metals basis

assay

≥99.99% trace metals basis

assay

99%

assay

99.99% trace metals basis

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

density

7.57 g/mL at 25 °C (lit.)

density

-

density

-

density

1.637 g/mL at 25 °C

impurities

≤1500 ppm Trace Metal Analysis

impurities

≤100.0 ppm Trace Metal Analysis

impurities

-

impurities

≤150.0 ppm Trace Metal Analysis

mp

289 °C (dec.) (lit.)

mp

-

mp

-

mp

-

Descripción general

Gold(I) chloride is a yellow crystalline solid with a monoclinic structure. It sublimes at elevated temperatures. Gold(III)chloride is thermally decomposed to produce gold(I) chloride. It is widely used as a precursor to prepare gold nanoparticles and catalyst systems.

Aplicación

Gold(I) chloride can be used:
  • As a precursor to prepare magnetic nanocatalyst systems for various organic transformations. For example, Fe3O4@SiO2-P–AuCl can be used as a catalyst for one-pot reductive amination of aldehydes and ketones with various aromatic amines.[1]
  • As a starting material to synthesize Au-containing complexes for application in the field of drug delivery, solar cells, sensors, and organic synthesis.[2]
  • As a precatalyst for stereoselective cycloisomerization of α-thioallenes to 2,5-dihydrothiophenes via C-S bond formation.[3]
  • As a catalyst for the conversion of siloxy cyclohexadienes, to the corresponding1,2- and 1,3-cyclohexenones via Gold-Catalyzed Cycloisomerization.[4]

Pictogramas

CorrosionExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Skin Corr. 1B - Skin Sens. 1

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificados de análisis (COA)

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Visite la Librería de documentos

Gold-Catalyzed Cycloisomerization of Siloxy Enynes to Cyclohexadienes
Liming Zhang and Sergey A. Kozmin
Journal of the American Chemical Society, 126, 11806-11807 (2004)
Based on magnetic nanoparticles: Gold reusable nanomagnetic catalysts in organic synthesis
Mosstafa Kazemi
Synthetic Communications, 50, 2079-2094 (2020)
The First Gold-Catalyzed C?S Bond Formation: Cycloisomerization of ?-Thioallenes to 2,5-Dihydrothiophenes
Nobuyoshi Morita
Angewandte Chemie (International Edition in English) (2006)
Au-containing coordination polymers based on polyphosphorus ligand complexes
Helena Brake, et al.
Inorganic Chemistry, 60, 6027-6039 (2021)
A comparative study of galvanic replacement reactions involving Ag nanocubes and AuCl2? or AuCl4?
Au L, et al.
Advanced Materials, 20(13), 2517-2517 (2008)

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Preguntas

1–2 de 2 Preguntas  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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