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Merck

221473

Hidróxido de potasio

ACS reagent, ≥85%, pellets

Potassium hydroxide

Sinónimos:

Potasa cáustica

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25 G

26,90 €

500 G

29,90 €

1 KG

50,50 €

2.5 KG

133,00 €

6 X 500 G

167,00 €

12 KG

580,00 €

26,90 €


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Fórmula lineal:
KOH
Número CAS:
Peso molecular:
56.11
Número CE:
Número MDL:
Código UNSPSC:
12352106
eCl@ss:
38100303
ID de la sustancia en PubChem:
NACRES:
NA.21

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grado

ACS reagent

Nivel de calidad

Agency

suitable for EPA 1621
suitable for EPA 1633

presión de vapor

1 mmHg ( 719 °C)

Ensayo

≥85%

Formulario

pellets

impurezas

≤0.001% N compounds
≤2.0% K2CO3
10-15% water

pH

~13.5 (25 °C, 5.6 g/L)

mp

361 °C (lit.)

solubilidad

water: soluble

trazas de anión

chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤5 ppm
sulfate (SO42-): ≤0.003%

trazas de catión

Ca: ≤0.005%
Fe: ≤0.001%
Mg: ≤0.002%
Na: ≤0.05%
Ni: ≤0.001%
heavy metals: ≤0.001% (by ICP)

aplicaciones

PFAS testing

temp. de almacenamiento

room temp

cadena SMILES

[OH-].[K+]

InChI

1S/K.H2O/h;1H2/q+1;/p-1

Clave InChI

KWYUFKZDYYNOTN-UHFFFAOYSA-M

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Este artículo
91106206103484016
form

pellets

form

pellets

form

powder

form

flakes

assay

≥85%

assay

≥85%

assay

≥85%

assay

90%

Quality Level

200

Quality Level

-

Quality Level

200

Quality Level

100

grade

ACS reagent

grade

ACS reagent

grade

-

grade

reagent grade

anion traces

chloride (Cl-): ≤0.01%, sulfate (SO42-): ≤0.003%, phosphate (PO43-): ≤5 ppm

anion traces

chloride (Cl-): ≤0.01%, phosphate (PO43-): ≤5 ppm, sulfate (SO42-): ≤0.003%

anion traces

chloride (Cl-): ≤1000 mg/kg, sulfate (SO42-): ≤50 mg/kg

anion traces

-

cation traces

Fe: ≤0.001%, Na: ≤0.05%, heavy metals: ≤0.001% (by ICP), Ca: ≤0.005%, Ni: ≤0.001%, Mg: ≤0.002%

cation traces

Ca: ≤0.005%, Fe: ≤0.001%, Mg: ≤0.002%, Na: ≤0.05%, Ni: ≤0.001%, heavy metals: ≤0.001% (by ICP-OES)

cation traces

Fe: ≤20 mg/kg

cation traces

-

Descripción general

Potassium hydroxide is an inorganic salt mainly used as a precursor to synthesize other potassium compounds such as potassium acetate,[1] potassium bicarbonate and potassium carbonate.[2] On a commercial scale, it is synthesized by the electrolysis of potassium chloride.[3]

Aplicación

Potassium hydroxide may be used in the following processes:
  • Conversion of nitriles to amide in tert-butanol.[4]
  • Cross-coupling of aryl halides with different sulfur-, oxygen- and nitrogen-based nucleophiles in dimethyl sulfoxide.[5]
  • As an activator for the preparation of activated carbons from corn cobs.[6]
  • As a base for the N-alkylation of nitrogen heterocycles in polyethylene glycol-ether solvents.[7]
  • Synthesis of (S)-1-(4-benzyl-2-thioxothiazolidin-3-yl)propan-1-one from (S)-phenylalaninol.[8]
  • To catalyze the polymerization of propylene oxide.[9]

Pictogramas

CorrosionExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Certificados de análisis (COA)

Lot/Batch Number

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Visite la Librería de documentos

Ledgard J
The Preparatory Manual of Explosives., 79-79 (2009)
Preparation of high surface area activated carbon from corn by chemical activation using potassium hydroxide
Bagheri N & Abedi J
Chemical Engineering Research and Design, 87(8), 1059-1064 (2009)
A study of the polymerization of propylene oxide catalyzed by anhydrous potassium hydroxide
Steiner EC, et al
Journal of the American Chemical Society, 86(21), 4678-4686 (1964)
Dimethyl Sulfoxide/Potassium Hydroxide: A Superbase for the Transition Metal-Free Preparation of Cross-Coupling Products
Yuan Y, et al
Advanced Synthesis & Catalysis, 352(17), 2892-2898 (2010)
Potassium acetate by fermentation with Clostridium thermoaceticum
Shah MM, et al.
Applied Biochemistry and Biotechnology (1997)

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Simultaneous LC-MS/MS determination of vitamins D₂ and D₃ in infant milk powder meeting GB 5009.296-2023 criteria for accuracy and sensitivity.

Preguntas

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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