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Merck

777072

Phthalimidomethyl butyl trithiocarbonate

97%

Synonym(s):

Butyl TTC protected amine RAFT, Protected methylamine butyl trithiocarbonate

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About This Item

Empirical Formula (Hill Notation):
C14H15NO2S3
CAS Number:
19194-21-9
Molecular Weight:
325.47
NACRES:
NA.23
PubChem Substance ID:
329767882
UNSPSC Code:
12352100
MDL number:
MFCD24386389

Key Documents

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Product Name

Phthalimidomethyl butyl trithiocarbonate, 97%

InChI

1S/C14H15NO2S3/c1-2-3-8-19-14(18)20-9-15-12(16)10-6-4-5-7-11(10)13(15)17/h4-7H,2-3,8-9H2,1H3

SMILES string

CCCCSC(=S)SCN1C(=O)c2ccccc2C1=O

InChI key

OUCYVVFRLVYRSW-UHFFFAOYSA-N

assay

97%

form

solid

mp

88-93 °C

storage temp.

2-8°C

Application

RAFT agent for controlled radical polymerization; Chain Transfer Agent (CTA)
Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCF4390
MKBN9949

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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