C3654

Ammonium cerium(IV) nitrate

Name: Ammonium cerium(IV) nitrate
Brand: SIGALD
Price: 17287.53 INR
Availability: InStock

≥98% (titration)

Synonym(s):

Ceric ammonium nitrate

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250 G

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GeM Catalogue ID: 5116877-38101699964

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About This Item

Linear Formula:

Ce(NH₄)₂(NO₃)₆

CAS Number:

16774-21-3

Molecular Weight:

548.22

EC Number:

240-827-6

MDL number:

MFCD00151121

UNSPSC Code:

12352302

PubChem Substance ID:

329775041

NACRES:

NA.55

Assay:

≥98% (titration)

Form:

powder or crystals

Key Documents

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Assay

≥98% (titration)

form

powder or crystals

reaction suitability

reagent type: oxidant

pH

0.61 (20 °C, 111.11 g/L)

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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This Item	229547	215473	1.02276
Sigma-Aldrich C3654 Ammonium cerium(IV) nitrate	Sigma-Aldrich 229547 Ammonium cerium(IV) nitrate	Sigma-Aldrich 215473 Ammonium cerium(IV) nitrate	Supelco 1.02276 Ammonium cerium(IV) nitrate
form powder or crystals	form crystalline	form powder or crystals	form crystalline
assay ≥98% (titration)	assay ≥99.99% trace metals basis	assay ≥98.5%	assay ≥99.0% ((NH₄)₂[Ce(NO₃)₆] basis, potentiometry)
Quality Level 100	Quality Level 200	Quality Level 200	Quality Level 300
pH 0.61 (20 °C, 111.11 g/L)	pH -	pH -	pH 0.61 (20 °C, 111.11 g/L in H₂O)
reaction suitability reagent type: oxidant	reaction suitability reagent type: oxidant	reaction suitability reagent type: oxidant	reaction suitability -

Pictograms

GHS03,GHS05,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H272,H290,H302,H314,H317,H410

Precautionary Statements

P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

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Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry.

Meng Zhou et al.

Journal of the American Chemical Society, 132(36), 12550-12551 (2010-08-25)

A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation

Building functionalized peptidomimetics: new electroauxiliaries and the use of a chemical oxidant for introducing N-acyliminium ions into peptides.

Haizhou Sun et al.

Organic letters, 5(18), 3189-3192 (2003-08-29)

[reaction: see text] The removal of electroauxiliaries from peptide substrates with chemical oxidants has been examined as a method for inserting N-acyliminium ions into the peptides. To this end, it was found that both 4-methoxyphenyldimethylsilyl and 2,4-dimethoxyphenyldimethylsilyl electroauxiliaries were readily

Ultrasound assisted synthesis of tetrahydrobenzo[c]xanthene-11-ones using CAN as catalyst.

S Sudha et al.

Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)

Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.

Recent advances in synthetic transformations mediated by cerium(IV) ammonium nitrate.

Vijay Nair et al.

Accounts of chemical research, 37(1), 21-30 (2004-01-21)

Cerium(IV) ammonium nitrate (CAN) has recently emerged as a versatile reagent for oxidative electron transfer; the overwhelming number of reports serve as a testimony to the unparalleled utility of CAN in a variety of transformations of synthetic importance. Our recent

An efficient and general approach to beta-functionalized ketones.

Jingliang Jiao et al.

Organic letters, 9(7), 1323-1326 (2007-03-06)

[structure: see text]. The oxidation of selected anions (N3-, SCN-, I-, and Br-) by ceric ammonium nitrate (CAN) in the presence of substituted cyclopropyl alcohols provides a novel approach to beta-functionalized ketones. The protocol has a number of advantages including

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Ammonium cerium(IV) nitrate