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294837

Hydrogen chloride solution

1.0 M in diethyl ether

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About This Item

Empirical Formula (Hill Notation):
HCl
CAS Number:
7647-01-0
Molecular Weight:
36.46
NACRES:
NA.21
PubChem Substance ID:
329753358
UNSPSC Code:
12352301
MDL number:
MFCD00011324

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Product Name

Hydrogen chloride solution, 1.0 M in diethyl ether

InChI

1S/ClH/h1H

SMILES string

Cl

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

form

liquid

concentration

0.95-1.10 M (with NaOH, titration)
1.0 M in diethyl ether

density

0.731 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

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1 of 4

This Item
34554790964705551
Hydrogen chloride solution 1.0 M in diethyl ether

Sigma-Aldrich

294837

Hydrogen chloride solution

Hydrogen chloride solution 4.0 M in dioxane

Sigma-Aldrich

345547

Hydrogen chloride solution

Hydrogen chloride solution 3 M in methanol, derivatization grade (GC derivatization), LiChropur™

Supelco

90964

Hydrogen chloride solution

Hydrogen chloride solution 3 M in cyclopentyl methyl ether (CPME)

Sigma-Aldrich

705551

Hydrogen chloride solution

concentration

0.95-1.10 M (with NaOH, titration), 1.0 M in diethyl ether

concentration

3.80-4.40 M (by NaOH, titration), 4.0 M in dioxane

concentration

3 M in methanol

concentration

2.85-3.30 M (silver nitrate titration), 3 M in cyclopentyl methyl ether (CPME)

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

storage temp.

2-8°C

storage temp.

-

storage temp.

−20°C

storage temp.

2-8°C

density

0.731 g/mL at 25 °C

density

1.05 g/mL at 25 °C

density

0.871-0.881 g/mL at 20 °C

density

0.895 g/mL at 25 °C

Application

Hydrogen chloride solution (1.0 M in diethyl ether) can be used in the synthesis of molybdenum adamantylimido and t-butylimido alkylidene chloride complexes in the presence of PPh2Me. It is also used in some cyclization reactions, for example, in the cyclization of oxadiazole derivatives from corresponding thiosemicarbazides.

General description

Hydrogen chloride solution (1.0 M in diethyl ether) is generally prepared by passing HCl gas through diethyl ether solvent. It is suitable for air/moisture-sensitive reactions.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH019,EUH066

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0194
SHBS7100
SHBP5665
SHBP7725
SHBM4148

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Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. Do the 100-mL bottles of this reagent come with a Sure-Seal on top? Is it possible to ascertain this information from the pages somehow? Thanks!

    1 answer

    1. Yes, this product is packaged using SureSeal closures.

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  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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