Biphenyl

Name: Biphenyl
Brand: SIAL
Price: 101 PLN

PESTANAL^®, analytical standard

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1 G

PLN 101.00

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About This Item

Linear Formula:

C₆H₅C₆H₅

CAS Number:

92-52-4

Molecular Weight:

154.21

UNSPSC Code:

41116107

NACRES:

NA.24

PubChem Substance ID:

329755216

EC Number:

202-163-5

Beilstein/REAXYS Number:

1634058

MDL number:

MFCD00003054

Key Documents

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Product Name

Biphenyl, PESTANAL^®, analytical standard

InChI key

ZUOUZKKEUPVFJK-UHFFFAOYSA-N

InChI

1S/C12H10/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H

SMILES string

c1ccc(cc1)-c2ccccc2

grade

analytical standard

vapor density

5.31 (vs air)

vapor pressure

9.46 mmHg ( 115 °C)

product line

PESTANAL^®

autoignition temp.

1004 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

0.6 %, 111 °F
5.8 %, 166 °F

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

255 °C (lit.)

mp

68-70 °C (lit.)

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Show Differences

1 of 4

This Item	PHR2358	W312908	1073423
Supelco 35800 Biphenyl	Supelco PHR2358 Biphenyl	Sigma-Aldrich W312908 Biphenyl	USP 1073423 Biphenyl
format neat	format -	format -	format neat
technique(s) HPLC: suitable, gas chromatography (GC): suitable	technique(s) -	technique(s) -	technique(s) -
grade analytical standard	grade certified reference material, pharmaceutical secondary standard	grade -	grade pharmaceutical primary standard
product line PESTANAL^®	product line -	product line -	product line -
vapor density 5.31 (vs air)	vapor density 5.31 (vs air)	vapor density 5.31 (vs air)	vapor density 5.31 (vs air)
vapor pressure 9.46 mmHg ( 115 °C)	vapor pressure 9.46 mmHg ( 115 °C)	vapor pressure 9.46 mmHg ( 115 °C)	vapor pressure 9.46 mmHg ( 115 °C)

Application

Biphenyl may also serve as a polymerizable electrolyte additive for overcharge protection of lithium ion batteries.[1]

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

GHS07,GHS09

signalword

Warning

hcodes

H315,H319,H335,H410

pcodes

P261 - P264 - P271 - P273 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 2

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Electrochemical behavior of biphenyl as polymerizable additive for overcharge protection of lithium ion batteries

Xiao L, et al.

Electrochimica Acta, 49, 4189-4196 (2004)

Recyclable copper catalyzed nitrogenation of biphenyl halides: a direct approach to carbazoles.

Yang Ou et al.

Chemical communications (Cambridge, England), 49(33), 3473-3475 (2013-03-22)

A novel A21-CuI catalyzed direct nitrogenation of biphenyl halides for the direct synthesis of carbazoles via a direct C-H amination process has been developed. A recyclable and inexpensive Cu-catalyst was successfully employed in N-heterocyclic compound synthesis via tandem azidation and

Cross-coupling of diarylborinic acids and anhydrides with arylhalides catalyzed by a phosphite/N-heterocyclic carbene co-supported palladium catalyst system.

Xiaofeng Chen et al.

The Journal of organic chemistry, 77(17), 7572-7578 (2012-08-07)

A highly efficient cross-coupling of diarylborinic acids and anhydrides with aryl chlorides and bromides has been effected by using a palladium catalyst system co-supported by a strong σ-donor N-heterocyclic carbene (NHC), N,N'-bis(2,6-diisopropylphenyl) imidazol-2-ylidene, and a strong π-acceptor phosphite, triphenylphosphite, in

Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations.

Susan L Zultanski et al.

Journal of the American Chemical Society, 135(2), 624-627 (2013-01-04)

The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst (NiBr(2)·diglyme/4,4'-di-tert-butyl-2,2'-bipyridine, both commercially available) and represents the initial example of the use of a group 10 catalyst to cross-couple unactivated tertiary electrophiles

Identification of bacteria utilizing biphenyl, benzoate, and naphthalene in long-term contaminated soil.

Ondrej Uhlik et al.

PloS one, 7(7), e40653-e40653 (2012-07-19)

Bacteria were identified associated with biodegradation of aromatic pollutants biphenyl, benzoate, and naphthalene in a long-term polychlorinated biphenyl- and polyaromatic hydrocarbon-contaminated soil. In order to avoid biases of culture-based approaches, stable isotope probing was applied in combination with sequence analysis

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