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  • Synthesis, Crystal Structures, and Spectroscopic Characterization of Bis-aldehyde Monomers and Their Electrically Conductive Pristine Polyazomethines.

Synthesis, Crystal Structures, and Spectroscopic Characterization of Bis-aldehyde Monomers and Their Electrically Conductive Pristine Polyazomethines.

Polymers (2019-09-22)
Abdul Hafeez, Zareen Akhter, John F Gallagher, Nawazish Ali Khan, Asghari Gul, Faiz Ullah Shah
ABSTRAKT

Bis-aldehyde monomers 4-(4'-formyl-phenoxy)benzaldehyde (3a), 3-methoxy-4-(4'-formyl-phenoxy)benzaldehyde (3b), and 3-ethoxy-4-(4'-formyl-phenoxy)benzaldehyde (3c) were synthesized by etherification of 4-fluorobenzaldehyde (1) with 4-hydroxybenzaldehyde (2a), 3-methoxy-4-hydroxybenzaldehyde (2b), and 3-ethoxy-4-hydroxybenzaldehyde (2c), respectively. Each monomer was polymerized with p-phenylenediamine and 4,4'-diaminodiphenyl ether to yield six poly(azomethine)s. Single crystal X-ray diffraction structures of 3b and 3c were determined. The structural characterization of the monomers and poly(azomethine)s was performed by FT-IR and NMR spectroscopic techniques and elemental analysis. Physicochemical properties of polymers were investigated by powder X-ray diffraction, thermogravimetric analysis (TGA), viscometry, UV-vis, spectroscopy and photoluminescence. These polymers were subjected to electrical conductivity measurements by the four-probe method, and their conductivities were found to be in the range 4.0 × 10-5 to 6.4 × 10-5 Scm-1, which was significantly higher than the values reported so far.

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Sigma-Aldrich
4-Fluorobenzaldehyde, 98%