Hydrolysis studies of phosphodichloridate and thiophosphodichloridate ions.

Hydrolysis studies of phosphodichloridate and thiophosphodichloridate ions.

The Journal of organic chemistry (2012-06-12)

Richard J Delley, AnnMarie C O'Donoghue, David R W Hodgson

ABSTRAKT

We report the pH-k(obs) profiles for the hydrolyses of phosphodichloridate and thiophosphodichloridate ions in aqueous solutions. Both species show broad pH-k(obs) plateaus that extend to high pHs.

MATERIAŁY

Numer produktu

Marka

Opis produktu

201170

Sigma-Aldrich

Phosphorus(V) oxychloride, ReagentPlus^®, 99%

262099

Sigma-Aldrich

Phosphorus(V) oxychloride, 99.999%

224294

Sigma-Aldrich

Thiophosphoryl chloride, 98%