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Stereospecific Ni-catalyzed cross-coupling of potassium alkenyltrifluoroborates with alkyl halides.

Stereospecific Ni-catalyzed cross-coupling of potassium alkenyltrifluoroborates with alkyl halides.

Organic letters (2014-03-29)

Gary A Molander, O Andreea Argintaru

ABSTRAKT

A general method for the alkenylation of alkyl electrophiles using nearly stoichiometric amounts of the air- and moisture-stable potassium organotrifluoroborates has been developed. Various functional groups were tolerated on both the nucleophilic and electrophilic partner. Reactions of highly substituted E- and Z-alkenyltrifluoroborates, as well as vinyl- and propenyltrifluoroborates, were successful, and no loss of stereochemistry or regiochemistry was observed.

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Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

Sigma-Aldrich

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Sigma-Aldrich

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Sigma-Aldrich

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Nickel, powder, <50 μm, 99.7% trace metals basis

Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%

Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%

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Nickel, foil, not light tested, 100x100mm, thickness 0.004mm, hard, 99%

Nickel, wire reel, 10m, diameter 0.125mm, annealed, 99.98%

Nickel, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.99+%

Nickel, tube, 500mm, outside diameter 2.8mm, inside diameter 1.8mm, wall thickness 0.5mm, hard, 99.5%

Nickel, foil, 10mm disks, thickness 0.03mm, 99.9%

Nickel, foil, 0.2m coil, thickness 0.005mm, as rolled, 99.9%

Nickel, tube, 500mm, outside diameter 8.4mm, inside diameter 8.15mm, wall thickness 0.125mm, hard, 99.5%

Nickel, foil, 2m coil, thickness 0.075mm, as rolled, 99.98%

Nickel, foil, 0.5m coil, thickness 0.0125mm, annealed, 99%

Nickel, wire reel, 0.5m, diameter 0.05mm, as drawn, 99.99+%

Nickel, foil, 2m coil, thickness 0.25mm, annealed, 99.98%

Nickel, foil, 0.5m coil, thickness 0.15mm, annealed, 99%

Nickel, wire reel, 100m, diameter 0.5mm, as drawn, 99%

Nickel, foil, 10mm disks, thickness 0.1mm, annealed, 99%

Nickel, foil, 10mm disks, thickness 0.20mm, annealed, 99%

Nickel, foil, 10mm disks, thickness 0.5mm, as rolled, 100%

Nickel, rod, 200mm, diameter 30mm, 99%

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