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Migrated phthalate levels into edible oils.

Food additives & contaminants. Part B, Surveillance (2015-04-22)
Sana Sungur, Ramazan Okur, Faruk Hilmi Turgut, Ihsan Ustun, Cumali Gokce
RESUMEN

The determination of phthalates in edible oils (virgin olive oil, olive oil, canola oil, hazelnut oil, sunflower oil, corn oil) sold in Turkish markets was carried out using gas chromatography-mass spectrometry. Mean phthalate concentrations were between 0.102 and 3.863 mg L(-1) in virgin olive oil; 0.172 and 6.486 mg L(-1) in olive oil; 0.501 and 3.651 mg L(-1) in hazelnut oil; 0.457 and 3.415 mg L(-1) in canola oil; 2.227 and 6.673 mg L(-1) in sunflower oil; and 1.585 and 6.248 mg L(-1) in corn oil. Furthermore, the influence of the types of oil and container to the phthalate migration was investigated. The highest phthalate levels were measured in sunflower oil. The lowest phthalate levels were determined in virgin olive oil and hazelnut oil. The highest phthalate levels were determined in oil samples contained in polyethylene terephthalate.

MATERIALES
Número de producto
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Descripción del producto

Sigma-Aldrich
Dietilpirocarbonato, 96% (NT)
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Dibutyl phthalate, 99%
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Hexano, anhydrous, 95%
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Dioctyl phthalate, ≥99.5%
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Dess-Martin periodinane, 97%
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Diethyl phthalate, 99.5%
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Fosfato de sodio dibasic dodecahydrate, BioXtra, ≥99.0% (T)
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Dietilpirocarbonato, 96% (NT)
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Dimethyl phthalate, ≥99%
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Dietilpirocarbonato, 96% (NT)
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Dipropyl phthalate, 98%
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Hexano, JIS special grade, ≥96.0%
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Diethyl phthalate, ≥99%
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Dioctyl phthalate, ≥98.0% (GC)
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Hexano, HPLC Plus, for HPLC, GC, and residue analysis, ≥95%
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Dimethyl phthalate, ≥99%
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Fosfato de sodio dibasic dodecahydrate, JIS special grade, ≥99.0%
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Hexano, suitable for HPLC
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Hexano, SAJ first grade, ≥95.0%
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DBP, 98% (HPLC)
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Hexano, suitable for residue analysis, JIS 5000
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Hexano, JIS 300, ≥96.0%, suitable for residue analysis
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Hexano, JIS 1000, ≥96.0%, suitable for residue analysis
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Bis(2-ethylhexyl) phthalate, SAJ first grade, ≥98.0%
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Fosfato de sodio dibasic dodecahydrate, SAJ first grade, ≥98.0
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Dibutyl phthalate, SAJ special grade, ≥98.0%
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Dimethyl phthalate, SAJ special grade, ≥99.0%
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Hexano, ≥96.0%, suitable for residual phthalate analysis
Sigma-Aldrich
Diethyl phthalate, SAJ special grade, ≥98.0%