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469858

Tetrakis(dimethylamido)titan(IV)

99.999% trace metals basis

Synonym(e):

TDMAT, Tetrakis-(dimethylamino)-titan(IV)

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Ihnen/SKUVerfügbarkeitPreis
5 g
Warenkorb auf Verfügbarkeit prüfen
€ 232,00
25 g
Warenkorb auf Verfügbarkeit prüfen
€ 707,00

Über diesen Artikel

Lineare Formel:
[(CH3)2N]4Ti
CAS-Nummer:
Molekulargewicht:
224.17
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
221-904-3
MDL number:

€ 232,00


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Quality Segment

assay

99.999% trace metals basis

form

liquid

reaction suitability

core: titanium

bp

50 °C/0.5 mmHg (lit.)

density

0.947 g/mL at 25 °C (lit.)

SMILES string

CN(C)[Ti](N(C)C)(N(C)C)N(C)C

InChI

1S/4C2H6N.Ti/c4*1-3-2;/h4*1-2H3;/q4*-1;+4

InChI key

MNWRORMXBIWXCI-UHFFFAOYSA-N

General description

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Application

Tetrakis(dimethylamido)titan(IV) (TDMAT) ist ein Vorläufer von Titannitrid-(TiN)-Dünnfilmen mit metallorganischer chemischer Gasphasenabscheidung (OMCVD) und von Titandioxid-Dünnfilmen mit Atomlagenabscheidung (ALD).TDMAT durchläuft eine exotherme Reaktion mit einem Überschuss von Cyclopentadien und ergibt Tris(dimethylamido)(η5-cyclopentadienyl)titan(IV).

Features and Benefits

  • 99.999% trace metals basis ensures superior quality of deposited films, with minimal defects and consistent properties, critical for microelectronics and optoelectronics applications.
  • High purity reduces the risk of contamination during the coating process, leading to enhanced adhesion, durability, and performance of the final products.
  • The absence of impurities allows for the precise control of particle size and morphology, improving the effectiveness of nanoparticles in targeted applications.
  • High purity ensures that electronic properties are not compromised by impurities, enhancing device performance and reliability.
  • Controlling heavy metals at ppb levels ensures effective contamination control, regulatory compliance, and optimized performance.

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Dieser Artikel
669008455199553131
form

liquid

form

liquid

form

low-melting solid

form

-

assay

99.999% trace metals basis

assay

99.999% (trace metals analysis)

assay

≥99.99%

assay

≥99.99% trace metals basis

density

0.947 g/mL at 25 °C (lit.)

density

0.947 g/mL at 25 °C (lit.)

density

1.098 g/mL at 25 °C

density

1.049 g/mL at 25 °C (lit.)

bp

50 °C/0.5 mmHg (lit.)

bp

50 °C/0.5 mmHg (lit.)

bp

-

bp

81 °C/0.1 mmHg (lit.)

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

reaction suitability

core: titanium

reaction suitability

core: titanium

reaction suitability

core: hafnium

reaction suitability

core: zirconium


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pictograms

FlameCorrosion

signalword

Danger

supp_hazards

Lagerklasse

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

-22.0 °F - closed cup

flash_point_c

-30 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B - Water-react. 1


Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

3275-24-9

CAS No.


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Analysenzertifikate (COA)

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What sealing procedure was used for the ampule containing 469858-5G? There were issues when attempting to reseal the ampule using parafilm. Therefore, a resealing procedure is needed to ensure that the contents can be used over time without crystallizing.

    1 answer
    1. The ampules are intended for one-time use only. For any remaining material, it is advised to transfer it to a bottle with a screw cap in a glove bag under inert atmosphere instead of trying to re-seal the glass ampule. It's important to note that this material is highly sensitive to air and water, so it cannot be guaranteed that the material will not degrade once the ampule has been opened and the contents transferred to a new bottle.

      Helpful?

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