If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
346276
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
97%, solid
Synonym(s):
Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate
Select a Size
$111.00
$454.00
About This Item
Skip To
Product Name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 97%
SMILES string
[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F
InChI
1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1
InChI key
GNQXUMGHBSAQBV-UHFFFAOYSA-N
assay
97%
form
solid
mp
160 °C (dec.) (lit.)
reaction suitability
reagent type: catalyst
reagent type: catalyst
core: copper
reaction type: click chemistry
Quality Level
1 of 4
This Item | 407240 | 677892 | 493678 |
|---|---|---|---|
| reaction suitability core: copper, reagent type: catalyst | reaction suitability core: copper, reagent type: catalyst | reaction suitability core: copper, reagent type: catalyst | reaction suitability core: cobalt, reagent type: catalyst |
| assay 97% | assay 90% | assay 97% | assay 98% |
| form solid | form powder | form solid | form - |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 160 °C (dec.) (lit.) | mp 160 °C (dec.) (lit.) | mp - | mp 305 °C (dec.) (lit.) |
Application
It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.[2]
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].[3]
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.[4]
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.[5]
- In the synthesis of stimuli-responsive particle-based amphiphiles prepared by anisotropic click chemistry.[6]
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.
-
How can I determine the shelf life / expiration / retest date of this product?
1 answer-
Helpful?
-
-
How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Helpful?
-
Active Filters
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service