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1.06448

Sodium citrate, dihydrate

for analysis EMSURE® ACS,ISO,Reag. Ph Eur

Synonym(s):

Sodium citrate tribasic dihydrate, Trisodium Citrate, Sodium Citrate, Dihydrate, Citric acid trisodium salt dihydrate, Trisodium citrate dihydrate

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Size/SKUAvailabilityPrice
500 g
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$89.70
1 kg
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$138.00
5 kg
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$369.00
25 kg
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$1,550.00

About This Item

Linear Formula:
HOC(COONa)(CH2COONa)2 · 2H2O
CAS Number:
Molecular Weight:
294.10
UNSPSC Code:
12352107
NACRES:
NA.21
EC Index Number:
200-675-3
MDL number:
Beilstein/REAXYS Number:
6104939
Assay:
99.0-101.0% (perchloric acid titration), 99.0-101.0% anhydrous basis (perchloric acid titration)
Grade:
ACS reagent
Form:
solid

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grade

ACS reagent

Quality Segment

agency

reag. ISO, reag. Ph. Eur.

product line

EMSURE®

assay

99.0-101.0% (perchloric acid titration), 99.0-101.0% anhydrous basis (perchloric acid titration)

form

solid

potency

>8000 mg/kg LD50, oral (Rat)

composition

Water, 11-13%

impurities

≤0.005% Insoluble matter

pH

7.5-9.0 (25 °C, 50 g/L in H2O)

mp

150 °C (anhydrous substance), >300 °C (lit.)

bulk density

600 kg/m3

anion traces

chloride (Cl-): ≤0.001%, oxalate (C2O42-): ≤0.0300%, phosphate (PO43-): ≤0.002%, sulfate (SO42-): ≤0.004%

cation traces

Ca: ≤0.005%, Fe: ≤0.0005%, N: ≤0.001%, NH4+: ≤0.003%, heavy metals: ≤0.0005%, heavy metals (as Pb): ≤0.0005%

storage temp.

2-30°C

SMILES string

O.O.[Na+].[Na+].[Na+].OC(CC([O-])=O)(CC([O-])=O)C([O-])=O

InChI

1S/C6H8O7.3Na.2H2O/c7-3(8)1-6(13,5(11)12)2-4(9)10;;;;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;;;2*1H2/q;3*+1;;/p-3

InChI key

NLJMYIDDQXHKNR-UHFFFAOYSA-K

Application

Sodium citrate, dihydrate can be used as a:
  • Template in the preparation of cobalt oxide (Co3O4) anode materials via hydrothermal method.
  • Complexing agent in the synthesis of CdS nanocrystalline thin films.
  • Reducing agent in the synthesis of citrate-capped gold nanoparticles.
  • Buffering agent to maintain stable pH levels in desloratadine syrup formulation.

Analysis Note

Assay (perchloric acid titration): 99.0 - 101.0 %
Assay (Perchloric acid titration, calc. on anhydrous substance): 99.0 - 101.0 %
Identity: passes test
Appearance of solution: passes test
Insoluble matter: ≤ 0.005 %
pH-value (5 %; water; 25 °C): 7.5 - 9.0
Acidity or alkalinity: passes test
Chloride (Cl): ≤ 0.001 %
Oxalate (C₂O₄): ≤ 0.0300 %
Phosphate (PO₄): ≤ 0.002 %
Sulfate (SO₄): ≤ 0.004 %
Total nitrogen (N): ≤ 0.001 %
Heavy metals (ACS): ≤ 0.0005 %
Heavy metals (as Pb): ≤ 0.0005 %
Ca (Calcium): ≤ 0.005 %
Fe (Iron): ≤ 0.0005 %
NH₃ (Ammonia): ≤ 0.003 %
Readily carbonisable substance: passes test
Water: 11.0 - 13.0 %
Corresponds to ACS,ISO,Reag. Ph Eur

Other Notes

Replaces: SX0445; SX0445-1; SX0445-3; SX0445-5; SX0445-20

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


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Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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