Fortfahren mit
463558
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecan
Synonym(e):
Verkade Superbase
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| Packungsgröße | SKU | Verfügbarkeit | Preis |
|---|---|---|---|
| 1 g | Warenkorb auf Verfügbarkeit prüfen | € 285,00 | |
| 5 g | Warenkorb auf Verfügbarkeit prüfen | € 888,00 |
Über diesen Artikel
Empirische Formel (Hill-System):
C9H21N4P
CAS-Nummer:
Molekulargewicht:
216.26
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4970285
Technischer Dienst
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Unterstützung erhaltenmp
110-115 °C (lit.)
Quality Segment
SMILES string
CN1CCN2CCN(C)P1N(C)CC2
InChI
1S/C9H21N4P/c1-10-4-7-13-8-5-11(2)14(10)12(3)6-9-13/h4-9H2,1-3H3
InChI key
PCYSWBQHCWWSFW-UHFFFAOYSA-N
Application
Reactant involved in:
- Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies
- Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica
- Protection / deprotection strategies for diazeniumdiolate chemistry
- Encaging of the molecule to study change in its catalytic ability
- C-N coupling reactions
- Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane is involved as a reactant in:
- Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies.
- Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica.
- Protection / deprotection strategies for diazeniumdiolate chemistry.
- Encaging of the molecule to study the change in its catalytic ability.
- C-N coupling reactions.
- Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction.
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Dieser Artikel | |||
|---|---|---|---|
| Quality Level 100 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| mp 110-115 °C (lit.) | mp - | mp - | mp 132-136 °C (lit.) |
![2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane](/deepweb/assets/sigmaaldrich/product/structures/234/439/6e858589-146e-4f1e-968b-a50a4fa4ecf6/640/6e858589-146e-4f1e-968b-a50a4fa4ecf6.png)
![2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane](/deepweb/assets/sigmaaldrich/product/structures/387/021/edaffe12-6e4b-4305-9030-749551ac828a/640/edaffe12-6e4b-4305-9030-749551ac828a.png)
![2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 97%](/deepweb/assets/sigmaaldrich/product/structures/750/287/cc77a98e-fa6c-4d81-9f3e-f392770724ac/640/cc77a98e-fa6c-4d81-9f3e-f392770724ac.png)
![2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane hydrochloride 96%](/deepweb/assets/sigmaaldrich/product/structures/212/000/1e518dee-a971-42c1-affc-372525c41bd0/640/1e518dee-a971-42c1-affc-372525c41bd0.png)
Lagerklasse
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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[HP (HNCH2CH2) 3N] NO3: an efficient homogeneous and solid-supported promoter for aza and thia-Michael reactions and for Strecker reactions.
Fetterly B M, et al.
Tetrahedron, 62(2-3), 440-456 (2006)
Comprehensive Thermochemistry of W?H Bonding in the Metal Hydrides CpW (CO) 2 (IMes) H,[CpW (CO) 2 (IMes) H]?+, and [CpW (CO) 2 (IMes)(H) 2]+. Influence of an N-Heterocyclic Carbene Ligand on Metal Hydride Bond Energies.
Roberts J A, et al.
Journal of the American Chemical Society, 133(37), 14604-14613 (2011)
Novel protection?deprotection strategies in diazeniumdiolate chemistry: synthesis of V-IPA/NO.
Nandurdikar R S, et al.
Chemical Communications (Cambridge, England), 47(23), 6710-6712 (2011)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 463558-1G | 04061826723845 |
| 463558-5G | 04061833432167 |