Multinuclear palladium(II) complexes from P-C and P-Cl bond cleavage in (R(P),R(P)/S(P),S(P))-[PdCl2{1,2-(P(t)BuCl)2C2B10H10}].

Multinuclear palladium(II) complexes from P-C and P-Cl bond cleavage in (R(P),R(P)/S(P),S(P))-[PdCl2{1,2-(P(t)BuCl)2C2B10H10}].

Chemical communications (Cambridge, England) (2012-09-13)

Ilham Maulana, Peter Lönnecke, Evamarie Hey-Hawkins

ZUSAMMENFASSUNG

Two multinuclear palladium(II) complexes have been isolated as decomposition products resulting from P-Cl and P-C bond cleavage in (R(P),R(P)/S(P),S(P))-[PdCl(2){1,2-(P(t)BuCl)(2)C(2)B(10)H(10)}] in dichloromethane.

MATERIALIEN

Produktnummer

Marke

Produktbeschreibung

34856

Sigma-Aldrich

Dichlormethan, suitable for HPLC, ≥99.8%, contains amylene as stabilizer

D65100

Sigma-Aldrich

Dichlormethan, contains 40-150 ppm amylene as stabilizer, ACS reagent, ≥99.5%

650463

Sigma-Aldrich

Dichlormethan, HPLC Plus, for HPLC, GC, and residue analysis, ≥99.9%, contains 50-150 ppm amylene as stabilizer

270997

Sigma-Aldrich

Dichlormethan, anhydrous, ≥99.8%, contains 40-150 ppm amylene as stabilizer

320269

Sigma-Aldrich

Dichlormethan, ACS reagent, ≥99.5%, contains 40-150 ppm amylene as stabilizer

02575

Supelco

Dichlormethan, analytical standard

676853

Sigma-Aldrich

Dichlormethan, ACS reagent, ≥99.5%, contains 40-150 ppm amylene as stabilizer

439223

Sigma-Aldrich

Dichlormethan, suitable for HPLC, ≥99.9%, contains 40-150 ppm amylene as stabilizer

494453

Sigma-Aldrich

Dichlormethan, biotech. grade, 99.9%, contains 40-150 ppm amylene as stabilizer

66742

Supelco

Dichlormethan, Selectophore^™, ≥99.5%