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Merck

221945

Iodure de potassium

ACS reagent, ≥99.0%

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54,30 €

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70,80 €

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210,00 €

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862,00 €

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Date d'expédition estimée le01 décembre 2025Détails


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A propos de cet article

Formule linéaire :
KI
Numéro CAS:
Poids moléculaire :
166.00
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.21

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Qualité

ACS reagent

Niveau de qualité

Pression de vapeur

1 mmHg ( 745 °C)

Essai

≥99.0%

Forme

crystals

Impuretés

≤0.001% N compounds
≤0.005% insolubles

Perte

≤0.2% loss on drying

pH

6.0-9.2 (25 °C, 5%)

Pf

681 °C (lit.)

Solubilité

water: complete (ca.1,430 g/l at 25 °C (77 °F))

Traces d'anions

chloride, bromide (as Cl)-: ≤0.01%
iodate (IO3-): ≤3 ppm
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.005%

Traces de cations

Ba: ≤0.002%
Ca: ≤0.002%
Fe: ≤3 ppm
Mg: ≤0.001%
Na: ≤0.005%
heavy metals (as Pb): ≤5 ppm

Chaîne SMILES 

[K+].[I-]

InChI

1S/HI.K/h1H;/q;+1/p-1

Clé InChI

NLKNQRATVPKPDG-UHFFFAOYSA-M

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Cet article
746428207969793582
form

crystals

form

crystals

form

powder or crystals

form

powder or crystals

assay

≥99.0%

assay

≥99%

assay

99%

assay

99%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

grade

ACS reagent

grade

ACS reagent, anhydrous

grade

-

grade

anhydrous

mp

681 °C (lit.)

mp

681 °C (lit.)

mp

681 °C (lit.)

mp

681 °C (lit.)

cation traces

Ba: ≤0.002%, Fe: ≤3 ppm, Na: ≤0.005%, Ca: ≤0.002%, heavy metals (as Pb): ≤5 ppm, Mg: ≤0.001%

cation traces

Ba: ≤0.002%, Ca: ≤0.002%, Fe: ≤3 ppm, Mg: ≤0.001%, Na: ≤0.005%, heavy metals (as Pb): ≤5 ppm

cation traces

-

cation traces

-

Description générale

Potassium iodide is a water soluble inorganic salt that can be prepared by reacting hydrogen iodide and potassium bicarbonate.[1]

Application

Potassium iodide may be used as a catalyst in the following processes: Conversion of aromatic primary amines to the corresponding nitro compounds in the presence of tert-butyl hydroperoxide as oxidant.[2] Conversion of aryl halide to aryl iodides in the presence of nickel catalysts.[3] Preparation of sulfonated oxindoles from activated alkenes and sulfonylhydrazides in water and in the presence of 8-crown-6 and tert-butyl hydroperoxide.[4]

Informations légales

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictogrammes

Health hazard

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

STOT RE 1 Oral

Organes cibles

Thyroid

Code de la classe de stockage

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Certificats d'analyse (COA)

Lot/Batch Number

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Consulter la Bibliothèque de documents

Synthesis of sulfonated oxindoles by potassium iodide catalyzed arylsulfonylation of activated alkenes with sulfonylhydrazides in water.
<BIG>Li X, et al. </BIG>
The Journal of Organic Chemistry, 78(14), 7343-7348 (2013)
Selective Oxidation of Aromatic Amines to Nitro Derivatives using Potassium Iodide-tert-Butyl Hydroperoxide Catalytic System
Reddy KR, et al
Advanced Synthesis & Catalysis, 351(1-2), 93-96 (2009)
Synthesis of Aryl Iodides from Aryl Halides and Potassium Iodide by Means of Nickel Catalyst
Takagi K, et al
Chemistry Letters (Jpn), 7(2), 191-192 (1978)
Eagleson M.
Concise Encyclopedia Chemistry, 889-889 (1994)
Alumina-supported potassium iodide as a heterogeneous catalyst for biodiesel production from soybean oil.
Xie W and Li H.
J. Mol. Catal. A: Chem., 255(1), 1-9 (2006)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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