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Merck

249866

Titanium(IV) chloride solution

1.0 M in methylene chloride

Synonyme(s) :

Titanium tetrachloride

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A propos de cet article

Formule linéaire :
TiCl4
Numéro CAS:
7550-45-0
Poids moléculaire :
189.68
NACRES:
NA.55
PubChem Substance ID:
329752763
UNSPSC Code:
12352300
MDL number:
MFCD00011267
Form:
liquid

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Nom du produit

Titanium(IV) chloride solution, 1.0 M in methylene chloride

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

vapor pressure

24.09 psi ( 55 °C)
6.93 psi ( 20 °C)

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.95-1.10 M NaOH (titration)
1.0 M in methylene chloride

density

1.365 g/mL at 25 °C

Quality Level

100

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Cet article
404985208566697079
Titanium(IV) chloride solution 1.0 M in methylene chloride

Sigma-Aldrich

249866

Titanium(IV) chloride solution

Titanium(IV) chloride solution 0.09 M in 20% HCl

Sigma-Aldrich

404985

Titanium(IV) chloride solution

Titanium(IV) chloride ReagentPlus®, 99.9% trace metals basis

Sigma-Aldrich

208566

Titanium(IV) chloride

Titanium tetrachloride packaged for use in deposition systems

Sigma-Aldrich

697079

Titanium tetrachloride

form

liquid

form

liquid

form

liquid

form

liquid

Quality Level

100

Quality Level

100

Quality Level

100, 200

Quality Level

100

vapor pressure

24.09 psi ( 55 °C), 6.93 psi ( 20 °C)

vapor pressure

-

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

density

1.365 g/mL at 25 °C

density

1.099 g/mL at 25 °C

density

1.73 g/mL at 20 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

reaction suitability

reagent type: catalyst
core: titanium

reaction suitability

reagent type: catalyst
core: titanium

reaction suitability

reagent type: catalyst
core: titanium

reaction suitability

-

concentration

0.95-1.10 M NaOH (titration)

concentration

0.09 M in 20% HCl

concentration

-

concentration

-

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.[1]

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.[2] Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.[3]

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH014

Classe de stockage

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
SHBT2278
SHBT2279
SHBS9970
SHBT0293
SHBR6321

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Yang Chen et al.
ChemSusChem, 4(10), 1498-1503 (2011-09-29)
Mesoporous TiO₂ beads with diameters of 320±50, 550±50, and 830±40 nm, comprising interconnected and densely packed TiO₂ nanocrystals, were used as working electrodes for dye-sensitized solar cells (DSCs). These electrodes possess high surface areas and superior light-scattering properties, which are ideal
Bratindranath Mukherjee et al.
Nanoscale, 5(1), 269-274 (2012-11-20)
The surface treatment of an anodized TiO(2) nanotube (T_NT) is very desirable for enhancing its photoelectrochemical properties and often is a prerequisite to deposition of any overlying layer for photoactivity efficiency improvement. This study provides a comparative analysis of the
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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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