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Merck

449148

Potassium fluoride

anhydrous, powder, ≥99.9% trace metals basis

Synonyme(s) :

Potassium monofluoride, Potassium monofluoride (KF)

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5 G

190.00 CHF

25 G

719.00 CHF

190.00 CHF


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A propos de cet article

Formule linéaire :
KF
Numéro CAS:
Poids moléculaire :
58.10
Beilstein:
3902818
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23

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Niveau de qualité

Qualité

anhydrous

Essai

≥99.9% trace metals basis

Forme

powder

Pertinence de la réaction

core: potassium

Impuretés

≤1000.0 ppm Trace Metal Analysis

Pf

858 °C (lit.)

Solubilité

water: soluble (923 g/l at 18 °C (64 °F))

Traces de cations

Cr: 1.6 ppm
Cs: 7.3 ppm
Cu: 0 ppm
Fe: 7.9 ppm
Li: 0.4 ppm
Mg: 0.3 ppm
Na: 514.2 ppm
Rb: 44.4 ppm

Chaîne SMILES 

[F-].[K+]

InChI

1S/FH.K/h1H;/q;+1/p-1

Clé InChI

NROKBHXJSPEDAR-UHFFFAOYSA-M

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Cet article
2298146024060239
form

powder

form

powder and chunks

form

powder or crystals

form

powder or crystals

assay

≥99.9% trace metals basis

assay

≥99.97% trace metals basis

assay

≥99.0% (F)

assay

≥99.0% (F)

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

grade

anhydrous

grade

-

grade

-

grade

-

impurities

≤1000.0 ppm Trace Metal Analysis

impurities

≤300.0 ppm Trace Metal Analysis

impurities

-

impurities

≤0.01% free acid (as HF), ≤0.01% free alkali (as KOH), ≤0.1% potassium fluoro silicate (K2SiF6)

mp

858 °C (lit.)

mp

858 °C (lit.)

mp

858 °C (lit.)

mp

858 °C (lit.)

Description générale

Potassium fluoride is a white crystalline solid that is highly soluble in water. It is a strong base widely used in the field of catalysis, polymer synthesis, and semiconductor devices. [1] [2] KF has a relatively high melting point. It dissolves well in hydrofluoric acid. However, KF is insoluble in alcohol.

Application

A versatile fluoride ion source used in a study of ion-specific swelling and de-swelling of ampholytic polymer gels, in the room temperature oxidation of noble metals in HF, and in the measurement of electronic polarizabilities of ions in polymers of alkali halides.
Potassium fluoride can be used:
  • To fabricate CIGS thin films solar cells. Efficiency increased by up to 21.7% after KF postdeposition treatment. This was due to the formation of a K-containing layer on the CIGS surface, which resulted in increased surface reactivity due to the formation of a bilayer structure in which a K—In—Se species covers the CIGSe compound.[3]
  • To fabricate 2D vanadium carbide MXene for supercapacitor electrodes.[4]
  • To synthesize sulfonyl fluoride through electrochemical oxidative coupling.[5]
  • As an electrolyte additive for Li-ion batteries.[6]
  • As a catalyst for ring-opening fluorination of cyclic thioethers.[1]
  • To synthesize solid base catalysts, KF/Ca−Mg−Al hydrotalcite for the production of Biodiesel via transesterification reactions.[2]

Pictogrammes

Skull and crossbonesCorrosion

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Certificats d'analyse (COA)

Lot/Batch Number

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Macromolecules, 29, 8391-8391 (1996)
Biodiesel Synthesis Catalyzed by the KF/Ca?Mg?Al Hydrotalcite Base Catalyst
Lijing Gao, et al
Energy and Fuels, 24, 646-651 (2010)
An aryne triggered ring-opening fluorination of cyclic thioethers with potassium fluoride
Rong Fan, et al.
Chemical Communications (Cambridge, England), 54, 7081-7084 (2018)
Indian Journal of Physics, 70B, 311-311 (1996)
Eur. J. Solid State Inorg. Chem., 33, 809-809 (1996)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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