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8.08913

Zirconium(IV) chloride

anhydrous, for synthesis

Funkce v oblasti udržitelnosti

Synonyma:

Zirconium(IV) chloride, Zirconium tetrachloride

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Vybrat velikost

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Vám/SKUDostupnostCena
5 g
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1 380,00 Kč
250 g
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2 160,00 Kč
1 kg
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6 160,00 Kč

O této položce

Lineární vzorec:
ZrCl4
Číslo CAS:
Molekulová hmotnost:
233.04
UNSPSC Code:
12352302
EC Index Number:
233-058-2
NACRES:
NA.22
MDL number:
Grade:
synthesis grade
Form:
crystals

1 380,00 Kč


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grade

synthesis grade

Quality Segment

vapor pressure

1.3 hPa ( 190 °C)

form

crystals

potency

1688 mg/kg LD50, oral (Rat)

sustainability

Sustainability features

pH

<1 (20 °C in H2O, saturated aqueous solution)

mp

437 °C

density

2.80 g/cm3 at 15 °C

bulk density

1200 kg/m3

greener alternative category

storage temp.

2-30°C

SMILES string

[Zr](Cl)(Cl)(Cl)Cl

InChI

1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4

InChI key

DUNKXUFBGCUVQW-UHFFFAOYSA-J

General description

Zirconium(IV) chloride is a Lewis acid catalyst, widely used in organic synthesis for the preparation of useful key intermediates. Since it is a stable and environmentally friendly catalyst used in various chemical reactions such as carbon-carbon bond formation reactions, reduction reactions, protection, and deprotection reactions.

Application

Zirconium(IV) chloride can be used as a catalyst to synthesize:
  • β-amino alcohols by ring-opening of epoxides with aromatic amines.
  • β-amino analogs via conjugate addition of aliphatic amines to α,β-unsaturated ester, nitriles, and ketones.
  • 1,3,4-oxadiazole derivatives by cyclodehydration of 1,2-diacylhydrazines.
  • 3,4-Dihydropyrimidinone derivatives via Biginelli condensation reaction of aromatic aldehyde, β-ketoester, and urea.

Features and Benefits

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Analysis Note

Assay (argentometric): ≥ 98.0 %
Hafnium (Hf): ≤ 40 ppm
Identity (ICP-OES): passes test


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Piktogramy

Corrosion

Výstražné slovo

Danger

Hazard Classifications

Met. Corr. 1 - Skin Corr. 1B

Co se děje?

WGK 3

Bod vzplanutí (°F)

Not applicable

Bod vzplanutí (°C)

Not applicable

Kódy nebezpečí

supp_hazards

Skladovací třída

8B - Non-combustible corrosive hazardous materials



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Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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