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Merck

697079

Titanium tetrachloride

packaged for use in deposition systems

Sinónimos:

Titanium(IV) chloride, TTC, Titanium tetrachloride

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Fórmula lineal:
TiCl4
Número CAS:
Peso molecular:
189.68
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
231-444-5
MDL number:

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Nombre del producto

Titanium tetrachloride, packaged for use in deposition systems

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl

vapor pressure

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

assay

≥99.995% (trace metals analysis)

form

liquid

reaction suitability

core: titanium
reagent type: catalyst

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

Quality Level

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1 of 4

Este artículo
2085662498668.12382
form

liquid

form

liquid

form

liquid

form

liquid

assay

≥99.995% (trace metals analysis)

assay

99.9% trace metals basis

assay

-

assay

-

mp

−25 °C (lit.)

mp

−25 °C (lit.)

mp

-

mp

-24 °C

density

1.73 g/mL at 20 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

density

1.365 g/mL at 25 °C

density

1.728 g/cm3 at 20 °C

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

vapor pressure

24.09 psi ( 55 °C), 6.93 psi ( 20 °C)

vapor pressure

12 hPa ( 20 °C)

bp

135-136 °C (lit.)

bp

135-136 °C (lit.)

bp

-

bp

136 °C/1013 hPa

Application

Titanium tetrachloride may be used in the vapor synthesis of titania powder by oxidaition. [1] It may be used as a catalyst in cross[2] and asymmetric[3] aldol reactions. Other possible uses of titanium tetrachloride is in the synthesis of :
  • γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds,[4]
  • N-Phosphinoylimines and N-sulphonylimines from aromatic aldehydes,[3]
  • Homoallyl ethers from allylsilanes and acetals.6

General description

Atomic number of base material: 22 Titanium

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

Clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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M T Crimmins et al.
The Journal of organic chemistry, 66(3), 894-902 (2001-06-30)
Asymmetric aldol additions using chlorotitanium enolates of N-acyloxazolidinone, oxazolidinethione, and thiazolidinethione propionates proceed with high diastereoselectivity for the Evans or non-Evans syn product depending on the nature and amount of the base used. With 1 equiv of titanium tetrachloride and
The titanium tetrachloride induced synthesis of N-phosphinoylimines and N-sulphonylimines directly from aromatic aldehydes
Jennings WB and Lovely CJ
Tetrahedron, 47(29), 5561-5568 (1991)
New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride
Mukaiyama T, et al.
Journal of the American Chemical Society, 96(24), 7503-7509 null
Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride
Hosomi A and Sakurai H
Tetrahedron Letters, 17(16), 1295-1298 (1976)
Hossein Noyan et al.
PloS one, 10(6), e0130658-e0130658 (2015-06-23)
To understand the molecular pathways underlying the cardiac preconditioning effect of short-term caloric restriction (CR). Lifelong CR has been suggested to reduce the incidence of cardiovascular disease through a variety of mechanisms. However, prolonged adherence to a CR life-style is

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Preguntas

1–4 de 4 Preguntas  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Could you provide instructions on how to open the package for the product 697079 Titanium Tetrachloride, for deposition purposes? If available, could you send an instruction booklet for this product?

    1 respuesta
    1. There will be a VCR cap that needs to be removed, and when attaching to a deposition tool, a new VCR gasket needs to be used, followed by the proper tightening protocol.

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  4. What is the Department of Transportation shipping information for this product?

    1 respuesta
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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