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Merck

1.03701

Hexane

≥99% (GC), suitable for LC/MS, LiChrosolv®

Sinónimos:

n-Hexano

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Fórmula lineal:
CH3(CH2)4CH3
Número CAS:
Peso molecular:
86.18
Beilstein:
1730733
Número MDL:
Código UNSPSC:
41116105
Número índice de la CE:
203-777-6
NACRES:
NA.03
Bp:
69 °C (lit.)

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Nombre del producto

Hexano, hypergrade for LC-MS LiChrosolv®

densidad de vapor

~3 (vs air)

Nivel de calidad

presión de vapor

256 mmHg ( 37.7 °C)
5.2 psi ( 37.7 °C)
~132 mmHg ( 20 °C)

Línea del producto

LiChrosolv®

Ensayo

≥99% (GC)

Formulario

liquid

temp. de autoignición

453 °F

lim. expl.

7.7 %

técnicas

HPLC: suitable
LC/MS: suitable

impurezas

≤0.0002 meq/g Acidity
≤0.0002 meq/g Alkalinity
≤0.005% Water
≤10 ppb Al (Aluminium)
≤10 ppb Ca (Calcium)
≤10 ppb Fe (Iron)
≤10 ppb Mg (Magnesium)
≤10 ppb Na (Sodium)
≤5 ppb K (Potassium)

residuo de evap.

≤2.0 mg/L

transmitancia

210 nm, ≥60%
225 nm, ≥90%
245 nm, ≥98%

índice de refracción

n20/D 1.375 (lit.)

Viscosidad cinemática

0.50 cSt(20 °C)

bp

69 °C (lit.)

mp

−95 °C (lit.)

temperatura de transición

flash point -22 °C

densidad

0.659 g/mL at 25 °C (lit.)

temp. de almacenamiento

2-30°C

cadena SMILES

CCCCCC

InChI

1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3

Clave InChI

VLKZOEOYAKHREP-UHFFFAOYSA-N

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Este artículo
1.043691.007951.04371
Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

technique(s)

LC/MS: suitable

technique(s)

gas chromatography (GC): suitable

technique(s)

GC/MS: suitable

technique(s)

gas chromatography (GC): suitable

assay

≥99% (GC)

assay

≥99% (GC)

assay

≥98% (GC)

assay

≥98% (GC)

form

liquid

form

liquid

form

liquid

form

liquid

density

0.659 g/mL at 25 °C (lit.)

density

0.659 g/mL at 25 °C (lit.)

density

0.659 g/mL at 25 °C (lit.)

density

0.659 g/mL at 25 °C (lit.)

impurities

≤0.0002 meq/g Acidity, ≤0.005% Water, ≤10 ppb Ca (Calcium), ≤10 ppb Mg (Magnesium), ≤5 ppb K (Potassium), ≤0.0002 meq/g Alkalinity, ≤10 ppb Fe (Iron), ≤10 ppb Al (Aluminium), ≤10 ppb Na (Sodium)

impurities

≤0.005% Water, ≥99.9% Sum of hexane isomers + methylcyclopentane (GC)

impurities

-

impurities

-

Descripción general

The product is a high purity solvent that ensures baseline stability, lowest impurity levels and high UV transmittance in LC-MS applications.

Aplicación

Featured in screening and detection of estrogen-active nonylphenols in water by planar solid-phase extraction followed by high performance thin layer chromatography.
Also used in:
  • analysis of mineral oil saturated hydrocarbons in vegetable oils by LC-GC interface.[1]
  • studies on sugars and organic acids in biological matrices using GC coupled to triple quadruple mass spectrometry (QqQ-MS).[2]

Características y beneficios

  • no ghost peaks
  • full reproducibility
  • extends the lifetime of columns
  • optimized and tested for LC-MS applications
  • minimal background ion suppression
  • reduced risk of contamination
  • less exposure to hazardous chemicals

Nota de preparación

Product filtered through a 0.2 μm filter

Nota de análisis

Purity (GC): ≥ 99.0 %
Identity (IR): conforms
Evaporation residue: ≤ 2.0 mg/l
Water: ≤ 0.005 %
Acidity: ≤ 0.0002 meq/g
Alkalinity: ≤ 0.0002 meq/g
Al (Aluminium): ≤ 10 ppb
Ca (Calcium): ≤ 10 ppb
Fe (Iron): ≤ 10 ppb
K (Potassium): ≤ 5 ppb
Mg (Magnesium): ≤ 10 ppb
Na (Sodium): ≤ 10 ppb
Transmission (at 210 nm): ≥ 60 %
Transmission (at 225 nm): ≥ 90 %
Transmission (from 245 nm): ≥ 98 %
Suitable for LC-MS; Intensity of background mass peak based on reserpine(APCI/ESI positive): ≤ 2 ppb
Suitable for LC-MS; Intensity of background mass peak based on reserpine(APCI/ESI negative): ≤ 20 ppb
Filtered by 0,2 µm filter.

Otras notas

Explore various lab safety accessories and equipment for safe handling of solvents to increase your safety level from the first usage.

Información legal

LICHROSOLV is a registered trademark of Merck KGaA, Darmstadt, Germany

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Referencia del producto
Descripción
Precios

Palabra de señalización

Danger

Clasificaciones de peligro

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

Órganos de actuación

Central nervous system, Nervous system

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

-7.6 °F

Punto de inflamabilidad (°C)

-22 °C


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Quantification of sugars and organic acids in biological matrices using GC-QqQ-MS
Chemosphere, 207-223 (2018)
A lab-developed interface for liquid-gas chromatography coupling based on the use of a modified programmed-temperature-vaporizing injector
Zoccali M, et al.
Journal of Chromatography A, 1622, 461096-461096 (2020)

Artículos

Nonylphenols (NP) are ubiquitous substances that have been detected in highly diverse foodstuff. As breakdown products of nonylphenol ethoxylates, NP could end up in the aquatic environment. This article presents a rapid method for NP detection in surface water by planar solid phase extraction – planar yeast estrogen screen (pSPE-pYES).

Preguntas

1–2 de 2 Preguntas  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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