V697230

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

powder, Vetec^™

• Sinónimos: Pd(dppf)Cl₂
• Fórmula lineal: (C₁₇H₁₄P)₂Fe · PdCl₂
• Número CAS: 72287-26-4
• Peso molecular: 731.70
• UNSPSC Code: 12352300
• PubChem Substance ID: 329761901
• NACRES: NA.22
• MDL number: MFCD00015757

Propiedades

• Nombre del producto: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), Vetec^™
• Quality Segment: 100
• form: powder
• reaction suitability: core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling
• mp: 266-283 °C (lit.)
• storage temp.: room temp
• SMILES string: [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
• InChI key: JCWIWBWXCVGEAN-UHFFFAOYSA-L

Descripción

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl₂ may be used as an effective palladium catalyst in the following reactions:

• Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
• Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives
• Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes

For small scale and high throughput uses, product is also available as ChemBeads (919780)

Legal Information

Vetec is a trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• Clase de almacenamiento: 10 - Combustible liquids
• ¿Qué está pasando?: WGK 3
• Punto de inflamación (°F): Not applicable
• Punto de inflamación (°C): Not applicable