919780
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads
solid
Synonym(s):
Pd(dppf)Cl2
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
250 mg | Available to ship TODAY | $69.00 |
1 g | Available to ship TODAY | $148.00 |
About This Item
$69.00
Available to ship TODAYDetails
Product Name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads,
product line
ChemBeads
Quality Segment
form
solid
composition
~ 4 wt.% loading of catalyst
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
[Pd+2].[Fe+2].P(c6c[c-H]cc6)(c5ccccc5)c4ccccc4.P(c3c[c-H]cc3)(c2ccccc2)c1ccccc1.[Cl-].[Cl-]
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2
InChI key
NXQGGXCHGDYOHB-UHFFFAOYSA-L
Application
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (697230) & (931217)
Other Notes
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
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This Item | |||
|---|---|---|---|
| description - | description - | description - | description 97% |
| reaction suitability reagent type: catalyst | reaction suitability core: palladium, reaction type: Sonogashira Coupling, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst, core: nickel |
| form solid | form solid | form solid | form solid |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| composition ~ 4 wt.% loading of catalyst | composition - | composition ~ 5 wt.% loading of catalyst | composition - |
| product line ChemBeads | product line - | product line ChemBeads | product line - |
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads](/deepweb/assets/sigmaaldrich/product/structures/276/683/e8a8b162-1e17-467b-8eb6-f4180a60a1b9/640/e8a8b162-1e17-467b-8eb6-f4180a60a1b9.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane](/deepweb/assets/sigmaaldrich/product/structures/825/986/4317978b-1256-4c82-ab74-6a6a3ef948b1/640/4317978b-1256-4c82-ab74-6a6a3ef948b1.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloronickel(II) 97%](/deepweb/assets/sigmaaldrich/product/structures/274/566/a60d6584-163a-4c41-a738-60f8e4d524fa/640/a60d6584-163a-4c41-a738-60f8e4d524fa.png)
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Carc. 1B Inhalation
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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