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Merck

277258

2-Methylbutane

anhydrous, ≥99%

Synonym(s):

Isopentane

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About This Item

Linear Formula:
CH3CH2CH(CH3)2
CAS Number:
Molecular Weight:
72.15
UNSPSC Code:
12352001
NACRES:
NA.21
PubChem Substance ID:
EC Number:
201-142-8
Beilstein/REAXYS Number:
1730723
MDL number:
Grade:
anhydrous
Assay:
≥99%
Bp:
30 °C (lit.)
Vapor pressure:
11.17 psi ( 20 °C)

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Product Name

2-Methylbutane, anhydrous, ≥99%

InChI key

QWTDNUCVQCZILF-UHFFFAOYSA-N

InChI

1S/C5H12/c1-4-5(2)3/h5H,4H2,1-3H3

SMILES string

CCC(C)C

grade

anhydrous

vapor density

2.6 (vs air)

vapor pressure

11.17 psi ( 20 °C)

assay

≥99%

form

liquid

autoignition temp.

788 °F

expl. lim.

8.3 %

impurities

<0.001% water
<0.005% water (100 mL pkg)

evapn. residue

<0.0003%

refractive index

n20/D 1.354 (lit.)

bp

30 °C (lit.)

mp

-160 °C

density

0.62 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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1 of 4

This Item
32040427034259060
grade

anhydrous

grade

-

grade

-

grade

analytical standard

assay

≥99%

assay

≥99%

assay

≥99.5%

assay

≥99.7% (GC)

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

liquid

form

-

autoignition temp.

788 °F

autoignition temp.

788 °F

autoignition temp.

788 °F

autoignition temp.

788 °F

mp

-160 °C

mp

-160 °C

mp

-160 °C

mp

-

Application

2-Methylbutane undergoes catalytic dehydrogenation in the presence of chromia-alumina catalyst to form isoamylenes, which can undergo further dehydrogenation to form isoprene.[1] It may also be used as a solvent in the preparation of trans-Bis(triethylphosphine) (hydroxy carbonyl) (phenyl) platinum(II), a metallacarboxylic acid.[2]

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-59.8 °F - closed cup

flash_point_c

-51 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves


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Power efficient synthesis of isoprene via two-stage dehydrogenation of isopentane
Karimov OK &amp; Daminev RR
World Applied Sciences Journal , 24(3), 320-325 (2013)
Yiming Huang et al.
Transplantation, 89(6), 677-685 (2010-01-30)
The role of bone marrow (BM)-derived cells in pancreatic beta-cell regeneration remains unresolved. We examined whether BM-derived cells are recruited to the site of moderate pancreatic injury and contribute to beta-cell regeneration. Low-dose streptozotocin (STZ) treatment was used to induce
Synthesis, x-ray structural analysis, and thermal decomposition of the platinum (II) carboxylic acid (hydroxycarbonyl) trans-Pt (CO2H)(C6H5)(PEt3) 2. Formation of a diplatinum (II) complex containing carbon dioxide
Bennett MA, et al
Journal of the American Chemical Society, 110(21), 7098-7105 (1988)
Johnson AW.
Invitation to Organic Chemistry., 338-338 (1999)
Johnson AW.
Invitation to Organic Chemistry., 50-54 (1999)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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