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Merck

698989

聚(3-己基噻吩-2,5-二基)

regioregular, electronic grade, 99.995% trace metals basis, average Mn 15,000-45,000

别名:

Plexcore® OS 1100, P3HT

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线性分子式:
(C10H14S)n
化学文摘社编号:
UNSPSC Code:
12352103
MDL number:
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产品名称

聚(3-己基噻吩-2,5-二基), regioregular, electronic grade, 99.995% trace metals basis, average Mn 15,000-45,000

grade

electronic grade

assay

99.995% trace metals basis

form

solid

mol wt

average Mn 15,000-45,000

description

(>95% head-to-tail regioregular (HNMR))

mp

238 °C

solubility

chloroform, trichlorobenzene, chlorobenzene, toluene, and xylenes: soluble

fluorescence

λex 450 nm; λem 575 nm

orbital energy

HOMO 5 eV 
LUMO 3 eV 

OPV device performance

ITO/NiO/P3HT/PC61BM/LiF/Al

  • Short-circuit current density (Jsc): 11.3 mA/cm2
  • Open-circuit voltage (Voc): 0.64 V
  • Fill Factor (FF): 0.69
  • Power Conversion Efficiency (PCE): 5.16 %

ITO/PEDOT:PSS/P3HT:PC61BM (1:08)/Al
  • Short-circuit current density (Jsc): 9.5 mA/cm2
  • Open-circuit voltage (Voc): 0.63 V
  • Fill Factor (FF): 0.68
  • Power Conversion Efficiency (PCE): 5 %

PDI

≤2

semiconductor properties

P-type (mobility=10−4 - 10−1 cm2/V·s)

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General description

聚(3-己基噻吩)(P3HT)是一种区域规则的半导体聚合物。它主要用于有机电子,因为其规律的末端对末端的支链排列方式,使得共轭骨架能够有效地发生 Π-Π 堆积。由于存在烷基侧基,P3HT 在中性状态下变得疏水。
最高占据分子轨道能级为 5.1eV

Application

用于有机电子研究的高纯度P3HT。用于OFET和其他器件有源层的优化材料。聚(3-己基噻吩-2,5-二基)可以大量地作为场效应(FETs)和太阳能电池有机薄膜半导体层。,2

Legal Information

美国Plextronics公司产品,专利号6,166,172。
Plexcore is a registered trademark of Plextronics, Inc.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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"Control of active semiconducting layer packing in organic thin film transistors through synthetic tailoring of dielectric materials
Singh R, et al.
Royal Society of Chemistry Advances, 4(56), 29383-29392 (2014)
High sensitivity organic photodiodes with low dark currents and increased lifetimes
Ramuz, M.; Burgi, L.; Winnewisser, C.; et al.
Organic Electronics, 9, 369-376 (2008)
Lei Yang et al.
Physical chemistry chemical physics : PCCP, 14(2), 779-789 (2011-11-26)
Two hole conductor materials, spiro-OMeTAD and P3HT, were compared in solid-state dye-sensitized solar cells. Two organic dyes containing one anchor unit (D35) or two anchor units (M3) were used in the comparison. Absorbed photon to current conversion efficiency close to
Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology
Ma, W.; et al.
Advances in Functional Materials, 15, 1617-1622 (2005)
Flexible Transistors Exploiting P3HT on Paper Substrate and Graphene Oxide Film as Gate Dielectric: Proof of Concept.
Valentini L, et al.
Science of Advanced Materials, 5(5), 530-533 (2013)

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