E18425
氰乙酸乙酯
≥98%
别名:
α-氰基乙酸乙酯, 2-氰基乙酸乙酯, 3-乙氧基-3-氧代丙腈, 丙二酸乙酯腈, 氰基乙酸乙酯, 氰基乙酸酯, （乙氧基碳基）乙腈
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关于此项目
线性分子式:
NCCH2COOC2H5
化学文摘社编号:
分子量:
113.11
Beilstein:
605871
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
蒸汽密度
3.9 (vs air)
品質等級
蒸汽壓力
1 mmHg ( 67.8 °C)
化驗
≥98%
形狀
liquid
折射率
n20/D 1.418 (lit.)
bp
208-210 °C (lit.)
mp
−22 °C (lit.)
密度
1.063 g/mL at 25 °C (lit.)
SMILES 字串
CCOC(=O)CC#N
InChI
1S/C5H7NO2/c1-2-8-5(7)3-4-6/h2-3H2,1H3
InChI 密鑰
ZIUSEGSNTOUIPT-UHFFFAOYSA-N
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一般說明
氰基乙酸乙酯是酯。报道了氰基乙酸乙酯与醛的Knoevenagel 缩合反应。研究人员报道了氰基乙酸乙酯与醛、P2O5、哌啶和氯苯的微波增强Knoevenegal 缩合反应。
氰基乙酸乙酯广泛用作有机合成中的合成砌块，用于生成活性药物成分。
氰基乙酸乙酯广泛用作有机合成中的合成砌块，用于生成活性药物成分。
應用
氰基乙酸乙酯可用于合成乙醛酸乙酯。通过将氨基嫁接到 NaX和CsNaX 沸石上获得的沸石催化剂，并将其用于研究微反应器中的Knoevenagel 缩合反应。
包裝
封装在玻璃瓶中
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
230.0 °F
閃點（°C）
110 °C
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Yuya Oka et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(39), 9362-9368 (2017-05-18)
Mesoporous basic Mg-Al mixed metal oxides (MMOs) with a high surface area and large pore size have been prepared through the assembly of monodispersed layered double hydroxide nanoparticles (LDHNPs) with block copolymer templates. The particle sizes of the LDHNPs were
Microwave Enhanced Knoevenagel Condensation of Ethyl Cyanoacetate with Aldehydes.
Kim S-Y, et al.
Synthetic Communications, 27(4), 533-541 (1997)
Electrogenerated bases VII. Novel syntheses of ethyl glyoxalate and diethyl ketomalonate via electrogenerated superoxide.
Sugawara M and Baizer MM.
Tetrahedron Letters, 24(22), 2223-2226 (1983)
Korany A Ali et al.
Mini reviews in medicinal chemistry, 18(8), 717-727 (2017-04-27)
In this study, synthesis, molecular docking and anticancer screening of new series of substituted heterocycles with trimethoxy phenyl scaffold as Combretastatin analogues were described. Substituted pyridines were synthesized via the reaction of (E)-3-(dimethylamino)-1-(3,4,5- trimethoxyphenyl)prop-2-en-1-one (2) with active methylene reagents. Substituted
The Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate in the presence of CTMAB in water.
Wang S, et al.
Synthetic Communications, 31(5), 673-677 (2001)
商品
Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
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