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Merck

8.07485

Sigma-Aldrich

Polyethylene glycol

greener alternative

400, for synthesis

Synonym(s):

Poly(ethylene glycol), Polyglycol, Polyethylene oxide, Polyoxy ethylene, PEG 400, PEG

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50 ML
€29.80
1 L
€39.90
5 L
€133.00
25 KG
€483.00

€29.80


Estimated to ship on01 October 2025Details


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About This Item

Linear Formula:
H(OCH2CH2)nOH
CAS Number:
MDL number:
UNSPSC Code:
13111021
EC Index Number:
500-038-2
NACRES:
NA.22

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vapor pressure

<0.1 hPa ( 20 °C)

Quality Level

form

liquid

autoignition temp.

360 °C (DIN 51794)

potency

28000 mg/kg LD50, oral (Rat)
>20000 mg/kg LD50, skin (Rabbit)

greener alternative product characteristics

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

pH

5-7 (20 °C, 100 g/L in H2O)

kinematic viscosity

97-110 cSt(20 °C)

mp

5 °C

transition temp

flash point >200 °C

density

1.13 g/cm3 at 20 °C

greener alternative category

storage temp.

2-30°C

SMILES string

C(CO)O

InChI

1S/C2H6O2/c3-1-2-4/h3-4H,1-2H2

InChI key

LYCAIKOWRPUZTN-UHFFFAOYSA-N

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1 of 4

This Item
8.074868.074908.19015
form

liquid

form

liquid

form

solid

form

liquid

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

storage temp.

2-30°C

storage temp.

no temp limit

storage temp.

2-30°C

storage temp.

2-30°C

density

1.13 g/cm3 at 20 °C

density

1.13 g/cm3 at 20 °C

density

1.2 g/cm3 at 20 °C

density

1.21 g/cm3 at 20 °C

mp

5 °C

mp

17-22 °C

mp

53-58 °C

mp

55-58 °C

vapor pressure

<0.1 hPa ( 20 °C)

vapor pressure

<0.1 hPa ( 20 °C)

vapor pressure

<0.01 hPa ( 20 °C)

vapor pressure

<0.1 hPa ( 20 °C)

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. Polyethylene glycol (PEG) is an eco-friendly, biodegradable polymer widely used in pharmaceuticals and cosmetics. Its non-toxic nature and versatility make it a sustainable choice, derived from renewable resources, contributing to greener product formulations. Click here for more information.

Application

Polyethylene glycol 400 for synthesis. CAS 25322-68-3, pH 5 - 7 (100 g/l, H₂O, 20 °C).

Analysis Note

Density (d 20 °C/ 4 °C): 1.124 - 1.126
Hydroxyl value: 267 - 295
Average molecular mass: 380 - 420
Identity (IR): passes test
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

281.5 °F - closed cup

Flash Point(C)

138.6 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Related Content

Polyethylene glycol (PEG), also sometimes referred to as polyethylene oxide (PEO), is a condensation polymer of ethylene oxide and water that has several chemical properties that make it useful for biological, chemical and pharmaceutical applications.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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