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Merck

128422

mono-Ethyl fumarate

95%

Synonym(s):

Fumaric acid monoethyl ester, Monoethyl fumarate

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25 G

₪394.00

₪394.00


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About This Item

Linear Formula:
C2H5OCOCH=CHCOOH
CAS Number:
Molecular Weight:
144.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-544-7
Beilstein/REAXYS Number:
1723588
MDL number:

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Product Name

mono-Ethyl fumarate, 95%

InChI key

XLYMOEINVGRTEX-ONEGZZNKSA-N

InChI

1S/C6H8O4/c1-2-10-6(9)4-3-5(7)8/h3-4H,2H2,1H3,(H,7,8)/b4-3+

SMILES string

CCOC(=O)\C=C\C(O)=O

assay

95%

form

solid

bp

147 °C/16 mmHg (lit.)

mp

66-68 °C (lit.)

Quality Level

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This Item
651419M47353A26403
assay

95%

assay

97%

assay

95%

assay

99%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

solid

form

solid

form

liquid

form

liquid

mp

66-68 °C (lit.)

mp

144-145 °C (lit.)

mp

-

mp

7-9 °C (lit.)

bp

147 °C/16 mmHg (lit.)

bp

-

bp

150-151 °C/10 mmHg (lit.)

bp

162 °C/10 mmHg (lit.)

Application

mono-Ethyl fumarate (fumaric acid monoethyl ester, monoethyl fumarate) was used in the preparation of photo-crosslinkable macromers[1]. It was also used to synthesize Ugi/intramolecular Diels-Alder (IMDA) cycloaddition products[2].

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 1

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Janine Jansen et al.
Acta biomaterialia, 8(10), 3652-3659 (2012-06-19)
Photo-crosslinked networks were prepared from fumaric acid monoethyl ester-functionalized poly(D,L-lactic acid) oligomers and N-vinyl-2-pyrrolidone. Two model proteins, lysozyme and albumin, were incorporated into the network films as solid particles and their release behavior was studied. By varying the NVP content
Janine Jansen et al.
Biomacromolecules, 10(2), 214-220 (2008-12-19)
Polymer networks were prepared by photocross-linking fumaric acid monoethyl ester (FAME) functionalized, three-armed poly(D,L-lactide) oligomers using N-vinyl-2-pyrrolidone (NVP) as diluent and comonomer. The use of NVP together with FAME-functionalized oligomers resulted in copolymerization at high rates, and networks with gel
J Z Hu et al.
Solid state nuclear magnetic resonance, 6(1), 85-94 (1996-02-01)
The 1H magic-angle spinning (MAS) spectrum for a typical powdered solid is composed of a high resolution component and a broadline component. The high resolution component can be well isolated from the broadline component by the Hahn echo sequence with
Treatment of recurrent aphthous stomatitis with fumaric acid esters.
Emmanuella Guenova et al.
Archives of dermatology, 147(3), 282-284 (2011-03-23)
K Paulvannan
The Journal of organic chemistry, 69(4), 1207-1214 (2004-02-14)
An efficient approach to rigid tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels-Alder (IMDA) cycloaddition of pyrrole is described. The one-pot Ugi four-component condensation (4CC) reaction was used as the key transformation to prepare trienes with a carboxamide substituent

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