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Merck

480053

4-tert-Butylphenylboronic acid

≥95.0%

Synonym(s):

(p-tert-Butylphenyl)boronic acid, 4-t-Butylbenzeneboronic acid, 4-t-Butylphenylboronic acid, 4-tert-Butylbenzeneboronic acid, p-tert-Butylbenzeneboronic acid, [4-(1,1-Dimethylethyl)phenyl]boronic acid

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About This Item

Linear Formula:
(CH3)3CC6H4B(OH)2
CAS Number:
123324-71-0
Molecular Weight:
178.04
NACRES:
NA.22
PubChem Substance ID:
24871543
UNSPSC Code:
12352103
MDL number:
MFCD01009697

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Product Name

4-tert-Butylphenylboronic acid, ≥95.0%

InChI

1S/C10H15BO2/c1-10(2,3)8-4-6-9(7-5-8)11(12)13/h4-7,12-13H,1-3H3

SMILES string

CC(C)(C)c1ccc(cc1)B(O)O

InChI key

MNJYZNVROSZZQC-UHFFFAOYSA-N

assay

≥95.0%

mp

191-196 °C (lit.)

Quality Level

100

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This Item
417599417580523976
4-tert-Butylphenylboronic acid ≥95.0%

Sigma-Aldrich

480053

4-tert-Butylphenylboronic acid

4-Methoxyphenylboronic acid ≥95.0%

Sigma-Aldrich

417599

4-Methoxyphenylboronic acid

4-Vinylphenylboronic acid ≥95%

Sigma-Aldrich

417580

4-Vinylphenylboronic acid

4-Hydroxyphenylboronic acid ≥95.0%

Sigma-Aldrich

523976

4-Hydroxyphenylboronic acid

assay

≥95.0%

assay

≥95.0%

assay

≥95%

assay

≥95.0%

mp

191-196 °C (lit.)

mp

204-206 °C (lit.)

mp

190-193 °C (lit.)

mp

>230 °C (lit.)

Quality Level

100

Quality Level

200

Quality Level

-

Quality Level

100

Application

Cross-coupling building block used in synthesis of tetracycline derivatives.[1]

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ5650
SHBJ8483
SHBH0782V
0000001221
0000001516

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The Journal of Organic Chemistry, 68, 10199-10199 (2003)
Guillaume Erbland et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(71), 16328-16339 (2019-10-12)
The design and synthesis of two families of molecular-gear prototypes is reported, with the aim of assembling them into trains of gears on a surface and ultimately achieving controlled intermolecular gearing motion. These piano-stool ruthenium complexes incorporate a hydrotris(indazolyl)borate moiety
Xiao Yan et al.
Physical chemistry chemical physics : PCCP, 22(11), 6222-6230 (2020-03-05)
Unveiling the reaction mechanism is significant for developing high-performance catalysts. In this paper, a series of precisely controlled PdxM147-x (M = Cu, Pt, Au, Rh, Ru) dendrimer encapsulated nanoparticles (DENs) has been successfully synthesized. The mechanisms of PdxM147-x as catalysts
Heng Wang et al.
Chirality, 27(8), 523-531 (2015-04-25)
A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effect of chain conformation on the catalytic property. Its complex with Cu(OTf)(2) , i.e., Cu(II)-PA, was employed to catalyze the homogeneous Diels-Alder (D-A) reaction

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