C3654

Ammonium cerium(IV) nitrate

Name: Ammonium cerium(IV) nitrate
Brand: SIGALD
Price: 889 ILS

≥98% (titration)

Synonym(s):

Ceric ammonium nitrate

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250 G

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About This Item

Linear Formula:

Ce(NH₄)₂(NO₃)₆

CAS Number:

16774-21-3

Molecular Weight:

548.22

EC Number:

240-827-6

MDL number:

MFCD00151121

UNSPSC Code:

12352302

PubChem Substance ID:

329775041

NACRES:

NA.55

Assay:

≥98% (titration)

Form:

powder or crystals

Key Documents

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Assay

≥98% (titration)

form

powder or crystals

reaction suitability

reagent type: oxidant

pH

0.61 (20 °C, 111.11 g/L)

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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This Item	229547	215473	1.02276
Sigma-Aldrich C3654 Ammonium cerium(IV) nitrate	Sigma-Aldrich 229547 Ammonium cerium(IV) nitrate	Sigma-Aldrich 215473 Ammonium cerium(IV) nitrate	Supelco 1.02276 Ammonium cerium(IV) nitrate
form powder or crystals	form crystalline	form powder or crystals	form crystalline
assay ≥98% (titration)	assay ≥99.99% trace metals basis	assay ≥98.5%	assay ≥99.0% ((NH₄)₂[Ce(NO₃)₆] basis, potentiometry)
Quality Level 100	Quality Level 200	Quality Level 200	Quality Level 300
pH 0.61 (20 °C, 111.11 g/L)	pH -	pH -	pH 0.61 (20 °C, 111.11 g/L in H₂O)
reaction suitability reagent type: oxidant	reaction suitability reagent type: oxidant	reaction suitability reagent type: oxidant	reaction suitability -

Pictograms

GHS03,GHS05,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H272,H290,H302,H314,H317,H410

Precautionary Statements

P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

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Green and efficient synthesis of quinoxaline derivatives via ceric ammonium nitrate promoted and in situ aerobic oxidation of alpha-hydroxy ketones and alpha-keto oximes in aqueous media.

Ahmad Shaabani et al.

Chemical & pharmaceutical bulletin, 56(1), 79-81 (2008-01-08)

The direct conversion of alpha-hydroxy ketones and alpha-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green

Formation of gamma-lactones through CAN-mediated oxidative cleavage of hemiketals.

Alexander M Jacobine et al.

The Journal of organic chemistry, 73(18), 7409-7412 (2008-08-13)

The generation of substituted gamma-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an alpha-heteroatom.

Ceric ammonium nitrate promoted oxidation of oxazoles.

David A Evans et al.

Organic letters, 8(24), 5669-5671 (2006-11-17)

The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents

Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry.

Meng Zhou et al.

Journal of the American Chemical Society, 132(36), 12550-12551 (2010-08-25)

A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation

Building functionalized peptidomimetics: new electroauxiliaries and the use of a chemical oxidant for introducing N-acyliminium ions into peptides.

Haizhou Sun et al.

Organic letters, 5(18), 3189-3192 (2003-08-29)

[reaction: see text] The removal of electroauxiliaries from peptide substrates with chemical oxidants has been examined as a method for inserting N-acyliminium ions into the peptides. To this end, it was found that both 4-methoxyphenyldimethylsilyl and 2,4-dimethoxyphenyldimethylsilyl electroauxiliaries were readily

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Ammonium cerium(IV) nitrate