2-Amino-5-chloro-2′-fluorobenzophenone

Name: 2-Amino-5-chloro-2′-fluorobenzophenone
Brand: ALDRICH
Price: 14000 JPY

98%

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25 G

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About This Item

Linear Formula:

H₂NC₆H₃(Cl)C(O)C₆H₄F

CAS Number:

784-38-3

Molecular Weight:

249.67

EC Number:

212-316-8

MDL number:

MFCD00038381

UNSPSC Code:

12352100

PubChem Substance ID:

24864693

NACRES:

NA.22

Key Documents

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Assay

98%

mp

95-98 °C (lit.)

functional group

chloro
fluoro
ketone

SMILES string

Nc1ccc(Cl)cc1C(=O)c2ccccc2F

InChI

1S/C13H9ClFNO/c14-8-5-6-12(16)10(7-8)13(17)9-3-1-2-4-11(9)15/h1-7H,16H2

InChI key

GTGMXPIQRQSORU-UHFFFAOYSA-N

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1 of 4

This Item	T68101	543780	T64602
Sigma-Aldrich 397210 2-Amino-5-chloro-2′-fluorobenzophenone	Sigma-Aldrich T68101 3′,4′,5′-Trimethoxyacetophenone	Sigma-Aldrich 543780 5′-Fluoro-2′-hydroxy-3′-nitroacetophenone	Sigma-Aldrich T64602 2′,4′,6′-Trihydroxyacetophenone monohydrate
assay 98%	assay 98%	assay 98%	assay 98%
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
mp 95-98 °C (lit.)	mp 78-80 °C (lit.)	mp 87-90 °C (lit.)	mp 219-221 °C (lit.)
functional group chloro	functional group -	functional group fluoro, ketone, nitro	functional group -

Application

2-Amino-5-chloro-2′-fluorobenzophenone is suitable electrophilic coupling reagent for the determination of iron(III) in environmental waters, soils and industrial effluent samples. It may be used in the synthesis of following:

2,4-disubstituted quinolones, via Meyer-Schuster rearrangement[1]
6-chloro-2-methyl-4-(2-fluorophenyl) quinazoline[2]
N-desalkylflurazepam[2]
benzotriazepines[3]
diazepam-related benzodiazepines.[4]

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

397210-5G:
397210-25G:
397210-BULK:
397210-VAR:

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J. Chem. Res. Synop., 2-2 (1991)

Journal of the American Chemical Society, 112, 3969-3969 (1990)

Synthesis of the impurities during the manufacture of bulk drug midazolam and separation of these impurities by HPLC.

Bhawana Sati et al.

Acta pharmaceutica (Zagreb, Croatia), 63(3), 385-396 (2013-10-25)

During the manufacture of bulk drug midazolam various impurities arised that can be the related products or degradation products. Structures of eight impurities that can arise during the manufacture of bulk drug midazolam were proposed. In the present work, synthesis

Ionic liquid-an efficient recycalable system for the synthesis of 2, 4-disubstituted quinolines via Meyer-Schuster rearrangement.

Saqrma R and Prajapati D.

Synlett, 19, 3001-3005 (2008)

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