If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
249866
Titanium(IV) chloride solution
1.0 M in methylene chloride
Synonym(s):
Titanium tetrachloride
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About This Item
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Product Name
Titanium(IV) chloride solution, 1.0 M in methylene chloride
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
vapor pressure
24.09 psi ( 55 °C)
6.93 psi ( 20 °C)
form
liquid
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.95-1.10 M NaOH (titration)
1.0 M in methylene chloride
density
1.365 g/mL at 25 °C
Quality Level
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This Item | 254312 | 404985 | 208566 |
|---|---|---|---|
| form liquid | form liquid | form liquid | form liquid |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100, 200 |
| vapor pressure 24.09 psi ( 55 °C), 6.93 psi ( 20 °C) | vapor pressure 50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C) | vapor pressure - | vapor pressure 50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C) |
| density 1.365 g/mL at 25 °C | density 1.73 g/mL at 20 °C (lit.) | density 1.099 g/mL at 25 °C | density 1.73 g/mL at 20 °C (lit.) |
| reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst |
| concentration 0.95-1.10 M NaOH (titration) | concentration - | concentration 0.09 M in 20% HCl | concentration - |
Application
General description
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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