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Merck

410241

Sodium perchlorate

ACS reagent, ≥98.0%

Synonym(s):

Hyperchloric acid sodium salt

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100 G

¥8,330

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¥26,600

2.5 KG

¥88,900

¥8,330


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About This Item

Linear Formula:
NaClO4
CAS Number:
Molecular Weight:
122.44
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥98.0%
Grade:
ACS reagent
Form:
powder or chunks
Solubility:
water: soluble 2096 g/L at 20 °C

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grade

ACS reagent

Quality Level

Assay

≥98.0%

form

powder or chunks

reaction suitability

reagent type: oxidant

impurities

≤0.005% insolubles

pH

6.0-8.0 (25 °C, 5%)

mp

468 °C (lit.)

solubility

water: soluble 2096 g/L at 20 °C

anion traces

chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤0.002%

cation traces

Ca: ≤0.02%
Fe: ≤5 ppm
K: ≤0.05%
heavy metals: ≤5 ppm (by ICP)

SMILES string

[Na+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

BAZAXWOYCMUHIX-UHFFFAOYSA-M

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1 of 4

This Item
931950906700931969
form

powder or chunks

form

powder

form

powder

form

powder

solubility

water: soluble 2096 g/L at 20 °C

solubility

H2O: 209 g/dL at 15 °C

solubility

-

solubility

H2O: 59.8 g/dL at 25 °C

assay

≥98.0%

assay

≥99.9% trace metals basis

assay

≥98.0%

assay

≥99.9% trace metals basis

Quality Level

200

Quality Level

100

Quality Level

-

Quality Level

100

grade

ACS reagent

grade

anhydrous, battery grade

grade

ACS reagent

grade

anhydrous, battery grade

impurities

≤0.005% insolubles

impurities

≤1000 ppm (trace metals analysis)

impurities

-

impurities

≤1000 ppm (trace metals analysis)

General description

Sodium perchlorate is a water soluble perchlorate salt. It is prepared by electrolyzing aqueous sodium chlorate solution. It is a strong oxidizing agent.[1] On impregnating porous silicon with sodium perchlorate it forms an explosive composite which has been investigated.[2]

Application


  • Silica-Poly(Vinyl Alcohol) Composite Aerogel: A Promising Electrolyte for Solid-State Sodium Batteries.: This research highlights the use of sodium perchlorate in developing silica-poly(vinyl alcohol) composite aerogels, serving as an innovative electrolyte for solid-state sodium batteries. This study showcases the potential for advancements in energy storage technologies, emphasizing the role of sodium perchlorate in enhancing battery performance and safety (Vareda JP et al., 2024).


  • A sodium ion conducting gel polymer electrolyte with counterbalance between 1-ethyl-3-methylimidazolium tetrafluoroborate and tetra ethylene glycol dimethyl ether for electrochemical applications.: This research demonstrates the use of sodium perchlorate in developing a gel polymer electrolyte for sodium-ion batteries, providing a balance between conductivity and stability, crucial for the next generation of energy storage systems (Patel M et al., 2024).



  • Bendable quasi-solid-state aqueous sodium-ion batteries operated at -30 °C.: Utilizing sodium perchlorate, this study develops flexible and low-temperature operable sodium-ion batteries, offering significant advancements in portable and wearable electronic devices, highlighting the adaptability and efficiency of sodium perchlorate in extreme conditions (Gui Q et al., 2024).


Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1 - STOT RE 2

Target Organs

Thyroid

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 1: Oxidizing solids
Perchlorates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

410241-BULK:
410241-2.5KG:
410241-6X500G:
410241-12KG:
410241-500G:
410241-VAR:
410241-100G:


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Santaji Nalwade et al.
Scientia pharmaceutica, 79(1), 69-84 (2011-05-28)
A simple, precise and rapid stability-indicating ultra-performance liquid chromatography (UPLC) method is developed for the simultaneous quantitative determination of Telmisartan, Amlodipine besylate and Hydrochlorothiazide from their innovative poly pill combination drug product in the presence of degradation products. It involves
Changyong Zhang et al.
Water research, 145, 220-230 (2018-08-25)
Ammonia nitrogen removal from wastewaters has gained much attention in recent decades as a result of the environmental problems associated with discharge of excessive amounts of this critical nutrient including eutrophication of receiving waters, generation of offensive odours as a
Synthesis of sulfones using sodium perchlorate as a catalyst under neutral conditions.
Bandgar BP, et al.
New. J. Chem., 26(9), 1105-1107 (2002)
Cheng Ma et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(5), 1700996-1700996 (2018-06-08)
Solid-state polymer electrolytes (SPEs) with high ionic conductivity are desirable for next generation lithium- and sodium-ion batteries with enhanced safety and energy density. Nanoscale fillers such as alumina, silica, and titania nanoparticles are known to improve the ionic conduction of
Thermal analysis of the exothermic reaction between galvanic porous silicon and sodium perchlorate.
Becker CR, et al.
ACS Applied Materials & Interfaces, 2(11), 2998-3003 (2010)

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Do you have it on pharmaceutical grade, suitable for pharmacceutical formulations?

    1 answer
    1. This product is intended for research use only. Currently, there is no product option available that is suitable for pharmaceutical use.

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