Convergent total syntheses of fluvibactin and vibriobactin using molybdenum(VI) oxide-catalyzed dehydrative cyclization as a key step.

Convergent total syntheses of fluvibactin and vibriobactin using molybdenum(VI) oxide-catalyzed dehydrative cyclization as a key step.

Chemical communications (Cambridge, England) (2008-07-26)

Akira Sakakura, Shuhei Umemura, Kazuaki Ishihara

ZUSAMMENFASSUNG

Efficient total syntheses of fluvibactin and vibriobactin have been achieved via molybdenum(VI) oxide-catalyzed dehydrative cyclization, Sb(OEt)(3)-catalyzed ester-amide transformation, and WSCI and HOAt-promoted dehydrative amide formation.

MATERIALIEN

Produktnummer

Marke

Produktbeschreibung

331058

Sigma-Aldrich

Natriummolybdat Dihydrat, ACS reagent, ≥99%