Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chemical communications (Cambridge, England) (2012-10-16)

Daniel P Iwaniuk, Christian Wolf

ZUSAMMENFASSUNG

A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.

MATERIALIEN

Produktnummer

Marke

Produktbeschreibung

27470

Sigma-Aldrich

(±)-Citronellal, ≥95.0% (GC)

343641

Sigma-Aldrich

(R)-(+)-Citronellal, technical grade

373753

Sigma-Aldrich

(S)-(−)-Citronellal, 96%

W230715

Sigma-Aldrich

(±)-Citronellal, natural, ≥85%, FCC, FG

72638

Supelco

(±)-Citronellal, analytical standard