[Ir(dFppy)₂(dtbbpy)]PF₆

Name: [Ir(dFppy)<SUB>2</SUB>(dtbbpy)]PF<SUB>6</SUB>
Brand: ALDRICH
Price: 172000 CLP

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100 MG

$172.000

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Fórmula empírica (notación de Hill):

C₄₀H₃₆F₁₀IrN₄P

Número CAS:

1072067-44-7

Peso molecular:

985.92

MDL number:

MFCD31657504

UNSPSC Code:

51171641

NACRES:

NA.23

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form

powder or crystals

Quality Level

100

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

465 nm

SMILES string

[Ir+3]5([n+]6c(cc(cc6)C(C)(C)C)c7[n+]5ccc(c7)C(C)(C)C)(c3c(c(cc(c3)F)F)c4ncccc4)c1c(c(cc(c1)F)F)c2ncccc2.F[P-](F)(F)(F)(F)F

InChI

1S/C18H24N2.2C11H6F2N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-4,6-7H;;/q;;;-1;+5

InChI key

QHIBKCJQTBUWRW-UHFFFAOYSA-N

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Este artículo	912948	908568	911607
Sigma-Aldrich 901368 [Ir(dFppy)₂(dtbbpy)]PF₆	Sigma-Aldrich 912948 Ir[FCF₃(CF₃)ppy]₂(dtbbpy)PF₆	Sigma-Aldrich 908568 [Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆	Sigma-Aldrich 911607 [Ir(dFOMeppy)₂-(5,5′-dCF₃bpy)]PF₆
form powder or crystals	form powder	form powder or crystals	form powder or crystals
mp >300 °C	mp 378 °C	mp >300 °C	mp >300 °C
reaction suitability core: iridium	reaction suitability -	reaction suitability -	reaction suitability -
photocatalyst activation 465 nm	photocatalyst activation -	photocatalyst activation 460 nm	photocatalyst activation 465 nm
Quality Level 100	Quality Level 100	Quality Level -	Quality Level -

Application

This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

related product

Referencia del producto

Descripción

Precios

747769

[Ir(dtbbpy)(ppy)₂]PF₆

747793

(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆

804215

[Ir{dFCF₃ppy}₂(bpy)]PF₆

900540

Ir(dFppy)₃

900539

Ir[p-F(t-Bu)-ppy]₃

900538

Ir(p-F-ppy)₃

900570

Ir[dF(t-Bu)-ppy]₃

901409

[Ir(dF(Me)ppy)₂(dtbbpy)]PF₆

902217

Ir[dFFppy]₂-(4,4′-dCF₃bpy)PF₆, ≥95%

902225

Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆, ≥95%

904694

Ir(p-CF₃-ppy)₃, ≥95%

905518

Ir(dFFppy)₂(dtbbpy)PF₆

905917

(Ir[Me(Me)ppy]₂(dtbpy))PF₆

908568

[Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆, ≥95%

908703

[Ir(p-F(Me)ppy)₂-(4,4′-dtbbpy)]PF₆, ≥95%

922897

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆, ≥95%

Clase de almacenamiento

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number

MKCK9076

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Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3-sp2 Cross-Coupling of Oxalates with Aryl Halides.

Xiaheng Zhang et al.

Journal of the American Chemical Society (2016-10-11)

Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to

Microwave-Assisted Synthesis of Heteroleptic Ir(III)(+) Polypyridyl Complexes.

Timothy M Monos et al.

The Journal of organic chemistry, 81(16), 6988-6994 (2016-06-16)

We report a rapid, one-pot, operationally simple, and scalable preparation of valuable cationic heteroleptic iridium(III) polypyridyl photosensitizers. This method takes advantage of two consecutive microwave irradiation steps in the same reactor vial, avoiding the need for additional reaction purifications. A

Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.

Ladouceur S,et al.

European Journal of Inorganic Chemistry, 2013, 5329-5343 (2013)

Room-temperature decarboxylative alkynylation of carboxylic acids using photoredox catalysis and EBX reagents.

Franck Le Vaillant et al.

Angewandte Chemie (International ed. in English), 54(38), 11200-11204 (2015-07-28)

Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes from readily available carboxylic

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[Ir(dFppy)2(dtbbpy)]PF6