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Merck

206083

Ácido cloroplatínico hexahydrate

ACS reagent, ≥37.50% Pt basis

Sinónimos:

Cloruro platínico hexahydrate, Hexacloroplatinato (IV) de hidrógeno hexahydrate, Ácido hexacloroplatínico hexahydrate

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Fórmula lineal:
H2PtCl6 · 6H2O
Número CAS:
Peso molecular:
517.90
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.21

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grade

ACS reagent

form

powder or chunks

reaction suitability

reagent type: catalyst
core: platinum

concentration

≥37.5% Pt

solubility

alcohol: soluble

cation traces

alkalies and other metals: ≤0.05%

SMILES string

O.O.O.O.O.O.Cl.Cl.Cl[Pt](Cl)(Cl)Cl

InChI

1S/6ClH.6H2O.Pt/h6*1H;6*1H2;/q;;;;;;;;;;;;+4/p-4

InChI key

PIJUVEPNGATXOD-UHFFFAOYSA-J

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Este artículo
P5775P7082254029
grade

ACS reagent

grade

-

grade

-

grade

-

concentration

≥37.5% Pt

concentration

≥37.5% Pt (after Reduction with Mg, gravimetric)

concentration

≥37.5% Pt (gravimetric)

concentration

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

form

powder or chunks

form

powder and chunks

form

powder

form

-

solubility

alcohol: soluble

solubility

water: 100 mg/mL, clear to slightly hazy, yellow to orange

solubility

H2O: 0.5 M, clear, orange

solubility

-

cation traces

alkalies and other metals: ≤0.05%

cation traces

-

cation traces

Al: ≤0.0005%, Ca: ≤0.01%, Cu: ≤0.0005%, Fe: ≤0.001%, K: ≤0.005%, Mg: ≤0.005%, NH4+: ≤0.2%, Na: ≤0.01%, Pb: ≤0.001%, Zn: ≤0.0005%

cation traces

-

General description

El ácido cloroplatínico hexahidratado (H2PtCl6.6H2O) es una sal de platino inorgánica. Se han evaluado las frecuencias de resonancia de cuadrupolo puro del Cl35 en H2PtCl6.6H2O en investigaciones espectrofotométricas.[1]

Application

El ácido cloroplatínico hexahidratado puede utilizarse como un precursor del platino en la preparación de catalizadores de Pt sustentado por óxido de cerio (ceria)[2], nanocomposites[3] de TiO2/Pt, películas de carbón poroso impregnadas con nanopartículas de Pt[4] y sistema coloidal de sulfuro de cadmio-Pt.[5]
El ácido cloroplatínico hexahidratado se ha utilizado en los siguientes estudios:
  • Preparación de nanocubos de Pd (anchura de 150 nm) y nanosferas de Pt (diámetro de 150 nm).[6]
  • Para componer la disolución de plateado destinada a la electrodeposición de nanopartículas de Pt en nanoláminas en forma de pétalo de grafeno multicapa (MGPN).[7]
  • Síntesis de nano-composites de Pt y nano-carbón (NC).3

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Nuclear Quadrupole Resonance of Chlorine in Hexachloroplatinic (IV) Acid Hexahydrate and Sodium Hexachloroplatinate (IV) Hexahydrate.
Ito K, et al.
Bulletin of the Chemical Society of Japan, 35(3), 518-518 (1962)
Enhanced hydrogen evolution rates at high pH with a colloidal cadmium sulphide-platinum hybrid system.
Schneider J, et al.
APL Materials, 2(12), 126102-126102 (2014)
Electrospun functional micro/nanochannels embedded in porous carbon electrodes for microfluidic biosensing.
Mondal K, et al.
Sensors and Actuators B, Chemical, 229, 82-91 (2016)
Yanfang Geng et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 33(9), 993-998 (2017-09-12)
In the present study, we developed an electrochemical sensor for highly sensitive detection of hydroxylamine using Au-Pt alloy nanoparticles. Au-Pt alloy nanoparticles were electrochemically deposited on a working electrode made of single-walled carbon nanotubes. The framework composition in the Au-Pt
Bolin Chen et al.
ACS applied materials & interfaces, 8(45), 30941-30947 (2016-11-02)
Micro unmanned underwater vehicles (UUVs) need to house propulsion mechanisms that are small in size but sufficiently powerful to deliver on-demand acceleration for tight radius turns, burst-driven docking maneuvers, and low-speed course corrections. Recently, small-scale hydrogen peroxide (H2O2) propulsion mechanisms

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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