236071
N,N′-双(亚水杨基)乙二胺
98%
别名:
N,N′-双水杨醛缩乙二胺, 二亚水杨基乙二胺
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关于此项目
线性分子式:
(CH2N=CHC6H4OH)2
化学文摘社编号:
分子量:
268.31
Beilstein:
535296
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
化驗
98%
mp
127-128 °C (lit.)
溶解度
water: insoluble(lit.)
官能基
amine
imine
SMILES 字串
Oc1ccccc1\C=N\CC\N=C\c2ccccc2O
InChI
1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+
InChI 密鑰
VEUMANXWQDHAJV-JYFOCSDGSA-N
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一般說明
在丙酮溶液中，N,N′-双（亚水杨基）乙二胺 (salen) 与氯化铁反应生成络合物 (Fe salen Cl)。
應用
采用 N,N′-双（亚水杨基）乙二胺 (salen) 为配位剂，以流动注射火焰原子吸收光谱法 (FI-AAS) 在线预浓缩铜和铅。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Linus Chiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(44), 14117-14127 (2012-09-22)
Square-planar nickel(II) complexes of salen ligands, N,N'-bis(3-tert-butyl-(5R)-salicylidene)-1,2-cyclohexanediamine), in which R=tert-butyl (1), OMe (2), and NMe(2) (3), were prepared and the electronic structure of the one-electron-oxidized species [1-3](+·) was investigated in solution. Cyclic voltammograms of [1-3] showed two quasi-reversible redox waves
F Janati Fard et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 74-82 (2012-07-04)
Co(III) salen complex with N,N'-dipyridoxyl (1,4-butanediamine) Schiff-base ligand as tetradentate ligand was synthesized and characterized by the elemental and spectroscopic analysis. The interaction of this complex with calf thymus DNA (ct DNA) has been investigated in vitro using UV absorption
Structure and Paramagnetism of Five-and Six-Co-ordinate N: N' Bis-salicylidene Ethylenediamine Iron (III) Chloride.
Gerloch M, et al.
Nature, 212, 809-810 (1966)
Hydration of epoxides on [CoIII salen)] encapsulated in silica-based nanoreactors.
Bo Li et al.
Angewandte Chemie (International ed. in English), 51(46), 11517-11521 (2012-10-16)
Mohammad Azam et al.
Dalton transactions (Cambridge, England : 2003), 41(35), 10854-10864 (2012-08-04)
We have reported the synthesis of a novel salen ligand and its mononuclear Pd-salen complexes derived from 2-{[2-hydroxy-3-{[(E)-(2-hydroxyphenyl)methylidene]amino}propyl)imino]methyl}phenol. The newly synthesized and isolated Pd(II) complexes have been identified and fully characterized by various physico-chemical studies viz., elemental analyses, IR, UV-Vis
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