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Merck

697079

四氯化钛

packaged for use in deposition systems

别名:

氯化钛（IV）, TTC, 四氯化钛

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关于此项目

线性分子式:
TiCl4
化学文摘社编号:
7550-45-0
分子量:
189.68
NACRES:
NA.23
PubChem Substance ID:
329761885
UNSPSC Code:
12352103
EC Number:
231-444-5
MDL number:
MFCD00011267

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产品名称

四氯化钛, packaged for use in deposition systems

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl

vapor pressure

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

assay

≥99.995% (trace metals analysis)

form

liquid

reaction suitability

core: titanium
reagent type: catalyst

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

Quality Level

100

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相关类别

Application

四氯化钛可用于通过氧化作用气相合成二氧化钛粉末。 它可用作交叉和不对称羟醛缩合反应的催化剂。四氯化钛的其它可能用途是合成：
  • γ来自烯丙基硅烷和羰基化合物的δ不饱和醇，
  • 来自芳香醛的N-膦酰亚胺和N-磺酰亚胺，
  • 来自烯丙基硅烷和缩醛的高烯丙基醚。6

General description

基础材料的原子序数：22钛

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH014

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBD2091V
SHBJ5474
SHBG0527V
SHBB0888V
32696KMV

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M T Crimmins et al.
The Journal of organic chemistry, 66(3), 894-902 (2001-06-30)
Asymmetric aldol additions using chlorotitanium enolates of N-acyloxazolidinone, oxazolidinethione, and thiazolidinethione propionates proceed with high diastereoselectivity for the Evans or non-Evans syn product depending on the nature and amount of the base used. With 1 equiv of titanium tetrachloride and
The titanium tetrachloride induced synthesis of N-phosphinoylimines and N-sulphonylimines directly from aromatic aldehydes
Jennings WB and Lovely CJ
Tetrahedron, 47(29), 5561-5568 (1991)
New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride
Mukaiyama T, et al.
Journal of the American Chemical Society, 96(24), 7503-7509 null
Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride
Hosomi A and Sakurai H
Tetrahedron Letters, 17(16), 1295-1298 (1976)
Hossein Noyan et al.
PloS one, 10(6), e0130658-e0130658 (2015-06-23)
To understand the molecular pathways underlying the cardiac preconditioning effect of short-term caloric restriction (CR). Lifelong CR has been suggested to reduce the incidence of cardiovascular disease through a variety of mechanisms. However, prolonged adherence to a CR life-style is
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