360554
硝基甲烷
ACS reagent, ≥95%
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经验公式（希尔记法）:
CH3NO2
化学文摘社编号:
分子量:
61.04
UNSPSC Code:
12352102
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-876-6
Beilstein/REAXYS Number:
1698205
MDL number:
Grade:
ACS reagent
Assay:
≥95%
Bp:
101.2 °C (lit.)
Vapor pressure:
2.7 mmHg ( 20 °C)
产品名称
硝基甲烷, ACS reagent, ≥95%
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
InChI
1S/CH3NO2/c1-2(3)4/h1H3
SMILES string
C[N+]([O-])=O
grade
ACS reagent
vapor density
2.1 (vs air)
vapor pressure
2.7 mmHg ( 20 °C)
assay
≥95%
form
liquid
autoignition temp.
784 °F
expl. lim.
7.3 %, 33 °F
dilution
(for analytical testing)
impurities
≤0.05% water
color
APHA: ≤10
refractive index
n20/D 1.382 (lit.)
pH
6.4 (20 °C, 0.01 g/L)
bp
101.2 °C (lit.)
mp
−29 °C (lit.)
density
1.127 g/mL at 25 °C (lit.)
suitability
clear for appearance
Quality Level
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Application
硝基甲烷可作为溶剂用于：
- FeCl3-催化的吲哚与醇傅-克烷基化反应。
- 钴催化的醛肟脱水生成腈反应。
- 醇生成羰基化合物的化学选择性氧化反应。
- 金催化的芳基取代炔烃的氢芳基化反应。
General description
硝基甲烷是一种脂肪族硝基化合物，通常用作化学加工和分析的溶剂。
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.
Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.
Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.
Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.
Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.
Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.
Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
存储类别
4.1A - Other explosive hazardous materials
wgk
WGK 2
flash_point_f
95.0 °F - closed cup
flash_point_c
35 °C - closed cup
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Eagleson M.
Concise Encyclopedia Chemistry, 696-696 (1994)
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