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  • Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chemical communications (Cambridge, England) (2012-10-16)
Daniel P Iwaniuk, Christian Wolf
ABSTRACT

A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.

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Sigma-Aldrich
(±)-Citronellal, ≥95.0% (GC)
Sigma-Aldrich
(R)-(+)-Citronellal, technical grade
Sigma-Aldrich
(S)-(−)-Citronellal, 96%
Sigma-Aldrich
(±)-Citronellal, natural, ≥85%, FCC, FG
Supelco
(±)-Citronellal, analytical standard