If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
1.00029
Acetonitrile
≥99.9% (GC), suitable for LC/MS, LiChrosolv®
Synonym(s):
ACN, Cyanomethane, Ethyl nitrile, Methyl cyanide
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Product Name
Acetonitrile, hypergrade for LC-MS LiChrosolv®
agency
suitable for ASTM® 7968, suitable for ASTM® 7979, suitable for DIN 38407-42, suitable for EPA 1633, suitable for EPA 8327, suitable for GB 31604.35-2016, suitable for GB 5009.253-2016, suitable for ISO 21675 2019
reg. compliance
suitable for FDA C-010.02
Quality Level
InChI
1S/C2H3N/c1-2-3/h1H3
SMILES string
CC#N
InChI key
WEVYAHXRMPXWCK-UHFFFAOYSA-N
vapor density
1.41 (vs air)
vapor pressure
72.8 mmHg ( 20 °C), 97 hPa ( 20 °C)
product line
LiChrosolv®
assay
≥99.9% (GC)
form
liquid
autoignition temp.
524 °C, 973 °F
expl. lim.
16 %
technique(s)
HPLC: suitable, LC/MS: suitable
impurities
≤0.0001 meq/g Acidity, ≤0.0002 meq/g Alkalinity, ≤0.01% Water, ≤10 ppb Al (Aluminium), ≤10 ppb Ca (Calcium), ≤10 ppb Fe (Iron), ≤10 ppb Mg (Magnesium), ≤5 ppb Any further metal (ICP-MS), ≤5 ppb K (Potassium), ≤50 ppb Na (Sodium)
evapn. residue
≤1.0 mg/L
color
APHA: ≤10
transmittance
191 nm, ≥25%, 195 nm, ≥85%, 200 nm, ≥96%, 215 nm, ≥98%, 230 nm, ≥99%
refractive index
n20/D 1.344 (lit.)
bp
81-82 °C (lit.)
mp
−45 °C (lit.)
transition temp
flash point 2 °C
density
0.786 g/mL at 25 °C (lit.)
application(s)
PFAS testing
format
neat
storage temp.
2-30°C
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1 of 4
This Item | |||
|---|---|---|---|
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| assay ≥99.9% (GC) | assay ≥99.9% (GC) | assay ≥99.8% (GC) | assay ≥99.8% (GC) |
| technique(s) LC/MS: suitable | technique(s) HPLC: suitable | technique(s) HPLC: suitable | technique(s) gas chromatography (GC): suitable |
| form liquid | form liquid | form liquid | form liquid |
| density 0.786 g/mL at 25 °C (lit.) | density 0.786 g/mL at 25 °C (lit.) | density 0.786 g/mL at 25 °C (lit.) | density 0.786 g/mL at 25 °C (lit.) |
| vapor density 1.41 (vs air) | vapor density 1.41 (vs air) | vapor density 1.41 (vs air) | vapor density 1.41 (vs air) |
General description
Application
- Of the mobile phase in fast LC-MS quantification of illudane glycosides and analogs in bracken ferns.[1]
- In the elution mixture to extract (fluoro)quinolone antibiotic compounds from the SDB-RPS extraction cartridge.
Preparation Note
Other Notes
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
35.6 °F - closed cup
flash_point_c
2.0 °C - closed cup
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
Deleterious substance
pdsc
Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water soluble liquid
fsl
Substances Subject to be Indicated Names
ishl_indicated
Substances Subject to be Notified Names
ishl_notified
JP11000291000: + 1000299031: + 1000290000: + 1000294000: + 100029-BULK: + 1000299030: + 1000299010: + 1000292508: + 1000299187: + 1000292500:4548174002902 + 1000299185: + 1000291000:4548174002896 + 1000298891: + 1000294008:
jan
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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At spark-lab we have been using ACN for LC-MS / MS for years. It meets our quality requirements in 100%.
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